(1S,2R)-1-hydroxy-1,2,3,4-tetrahydrotetraphen-2-yl 4-chlorobenzoate

Base Information

Chemical Name:(1S,2R)-1-hydroxy-1,2,3,4-tetrahydrotetraphen-2-yl 4-chlorobenzoate
CAS No.:91366-00-6
Molecular Formula:C₂₅H₁₉ClO₃
Molecular Weight:402.877
Hs Code.:

Synonyms:

Suppliers and Price of (1S,2R)-1-hydroxy-1,2,3,4-tetrahydrotetraphen-2-yl 4-chlorobenzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2R)-1-hydroxy-1,2,3,4-tetrahydrotetraphen-2-yl 4-chlorobenzoate

Chemical Property:

Vapor Pressure:4.23E-16mmHg at 25°C
Boiling Point:617.4±55.0 °C(Predicted)
PKA:13.26±0.40(Predicted)
Density:1.38±0.1 g/cm3(Predicted)

Purity/Quality:

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Technology Process of (1S,2R)-1-hydroxy-1,2,3,4-tetrahydrotetraphen-2-yl 4-chlorobenzoate

There total 3 articles about (1S,2R)-1-hydroxy-1,2,3,4-tetrahydrotetraphen-2-yl 4-chlorobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

: 91423-71-1
(-)-cis-(1S,2R)-1,2-Dihydroxy-1,2,3,4-tetrahydrobenz anthracene

: 122-01-0
4-chloro-benzoyl chloride

: 91366-00-6
cis-(1S)-Hydroxy-(2R)-<(p-chlorobenzoyl)oxy>-1,2,3,4-tetrahydrobenz anthracene

: 91366-01-7
cis-(1S)-<(p-Chlorobenzoyl)oxy>-(2R)-hydroxy-1,2,3,4-tetrahydrobenz anthracene

Guidance literature:: In pyridine; for 3h; Ambient temperature;
DOI:10.1021/jo00193a033

Reference yield:

: 91422-87-6
3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1S,2R)-2-(3,3,3-trifluoro-2-methoxy-2-phenyl-propionyloxy)-1,2,3,4-tetrahydro-benzo[a]anthracen-1-yl ester

: 91366-00-6
cis-(1S)-Hydroxy-(2R)-<(p-chlorobenzoyl)oxy>-1,2,3,4-tetrahydrobenz anthracene

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / 1 M aq. NaOH/CH₃OH (1:1) / tetrahydrofuran / 24 h / Ambient temperature

2: 54 percent / pyridine / 3 h / Ambient temperature

With methanol; sodium hydroxide; In tetrahydrofuran; pyridine;
DOI:10.1021/jo00193a033

Reference yield:

: 60968-03-8,91422-90-1,91422-99-0,91423-71-1,94903-85-2,94903-86-3,106034-04-2,147200-22-4
1,2-Dihydroxy-1,2,3,4-tetrahydrobenz anthracene

: 91366-00-6
cis-(1S)-Hydroxy-(2R)-<(p-chlorobenzoyl)oxy>-1,2,3,4-tetrahydrobenz anthracene

Guidance literature:: Multi-step reaction with 3 steps

1: 40 percent / pyridine / 1) 0 deg C, 2 h, 2) ambient temperature, 10 h

2: 86 percent / 1 M aq. NaOH/CH₃OH (1:1) / tetrahydrofuran / 24 h / Ambient temperature

3: 54 percent / pyridine / 3 h / Ambient temperature

With methanol; sodium hydroxide; In tetrahydrofuran; pyridine;
DOI:10.1021/jo00193a033