Ni₃(CH₂C₆H₄CH₃)4(P(CH₃)3)2(OH)2

Base Information

Chemical Name:Ni₃(CH₂C₆H₄CH₃)4(P(CH₃)3)2(OH)2
CAS No.:98170-38-8
Molecular Formula:C₃₈H₅₆Ni₃O₂P₂
Molecular Weight:782.879
Hs Code.:

Ni<sub>3</sub>(CH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>)4(P(CH<sub>3</sub>)3)2(OH)2

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Chemical Property of Ni₃(CH₂C₆H₄CH₃)4(P(CH₃)3)2(OH)2

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Technology Process of Ni₃(CH₂C₆H₄CH₃)4(P(CH₃)3)2(OH)2

There total 10 articles about Ni₃(CH₂C₆H₄CH₃)4(P(CH₃)3)2(OH)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 108694-97-9
Ni(CH₂C₆H₄CH₃)2((CH₃)2NCH₂CH₂N(CH₃)2)

: 108694-95-7
(Ni(CH₂C₆H₄CH₃)(P(CH₃)3)(OH))2

: 594-09-2
trimethylphosphane

: 98170-38-8
Ni₃(CH₂C₆H₄CH₃)4(P(CH₃)3)2(OH)2

Guidance literature:: In diethyl ether; N2 atmosphere; a mixt. of the hydroxo complex and of a slight excess of the tmed complex were stirred in Et2O at room temp.; small amt. of PMe3 was added; the mixt. was stirred at room temp. for 2 h;; cooling at -30°C for 0.5 h; elem. anal.;;

Reference yield: 30.0%

: 37175-97-6,53177-14-3
tris(trimethylphosphine)nickel(II) chloride

: 29875-05-6
2-methylbenzylmagnesium chloride

: 98170-38-8
Ni₃(CH₂C₆H₄CH₃)4(P(CH₃)3)2(OH)2

Guidance literature:: With H₂O; In diethyl ether; N2 atmosphere; dichloro complex was treated with Grignard reagent in Et2O at -40°C; stirring for 4 h at room temp.;; removal of solvent under vac.; extn. with petroleum ether; centrifugation; concn.; addn. of a drop of water; cooling at -20°C for 48 h; elem. anal.;;

Reference yield: 30.0%

: 29875-05-6
2-methylbenzylmagnesium chloride

: 20087-67-6
dichlorobis(trimethylphosphine)nickel

: 98170-38-8
Ni₃(CH₂C₆H₄CH₃)4(P(CH₃)3)2(OH)2

Guidance literature:: In diethyl ether; byproducts: NiCl(η1-CH2C6H4CH3)(PMe3)2; NiCl2(PMe3)2 in Et2O was reacted at -40°C for ca. 30 min with 3 equiv of Mg(o-CH3C6H4CH2)Cl in Et2O, mixt. was stirred at room temp. for4 h; solvent was removed in vacuo, residue extd. with petroleum ether, ext. concd., a drop of water was added, cooled at -30°C for 48 h; contaminated with small amts. of mononuclear complex;