[Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)(η2-(methyl acrylate))][BPh4]

Base Information

• Chemical Name: [Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)(η2-(methyl acrylate))][BPh4]
• CAS No.: 474267-90-8
• Molecular Formula: C₁₃H₂₉CuN₃O₂*C₂₄H₂₀B
• Molecular Weight: 642.172
• Mol file: 474267-90-8.mol

Synonyms:

Chemical Property of [Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)(η2-(methyl acrylate))][BPh4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)(η2-(methyl acrylate))][BPh4]

There total 1 articles about [Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)(η2-(methyl acrylate))][BPh4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.1%

N,N,N',N'',N'''-pentamethyldiethylenetriamine (3030-47-5) + sodium tetraphenyl borate (143-66-8) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + copper(I) bromide (7787-70-4) → [Cu(N,N,N',N'',N''-pentamethyldiethylenetriamine)(η2-(methyl acrylate))][BPh4] (474267-90-8)

Guidance literature:

In methanol; acetone; under N2 atm. using Schlenk techniques; CuBr added to soln. of Me2NCH2CH2N(Me)CH2CH2NMe2 in MeOH/acetone at room temp.; one equiv. of α-olefin monomer added; 1 equiv. of NaBPh4 adeed at room temp.; ppt. dissolved by warming soln. to 40°C; cooled in ice bath; crystals were obtained; ppt. filtered; washed (cold MeOH); dried (vac.) for 12 h;

DOI:10.1016/j.jorganchem.2004.10.035

upstream raw materials:

N,N,N',N'',N'''-pentamethyldiethylenetriamine

sodium tetraphenyl borate

acrylic acid methyl ester

copper(I) bromide