[(C₅H₅)Os(NHC(C₆H₄Cl)CHC(CH₃))(PH(CH(CH₃)2)2)]

Base Information

• Chemical Name: [(C₅H₅)Os(NHC(C₆H₄Cl)CHC(CH₃))(PH(CH(CH₃)2)2)]
• CAS No.: 849116-06-9
• Molecular Formula: C₂₁H₂₉ClNOsP
• Molecular Weight: 552.095
• Mol file: 849116-06-9.mol

Synonyms:

Chemical Property of [(C₅H₅)Os(NHC(C₆H₄Cl)CHC(CH₃))(PH(CH(CH₃)2)2)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [(C₅H₅)Os(NHC(C₆H₄Cl)CHC(CH₃))(PH(CH(CH₃)2)2)]

There total 1 articles about [(C₅H₅)Os(NHC(C₆H₄Cl)CHC(CH₃))(PH(CH(CH₃)2)2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

sodium tetrahydroborate (16940-66-2) + [(C5H5)OsCl(NHC(C6H4Cl)CHC(CH3)P(CH(CH3)2)2)] (849116-03-6) → [(C5H5)Os(NHC(C6H4Cl)CHC(CH3))(PH(CH(CH3)2)2)] (849116-06-9)

Guidance literature:

In methanol; toluene; Schlenk-tube technique; soln. of Os complex in toluene was treated with NaBH4 (8 equiv.); methanol was added; mixt. was reacted at room temp. for 10 min; solvent removed; extd. (pentane); evapd.;

DOI:10.1021/om049178a

Reference yield: 82.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + [(C5H5)Os(NHC(C6H4Cl)CHC(CH3))(PH(CH(CH3)2)2)] (849116-06-9) → [(C5H5)OsH(NHC(C6H4Cl)CHC(CH3))(PH(CH(CH3)2)2)]

Guidance literature:

In diethyl ether; Schlenk-tube technique; soln. of Os complex in Et2O was treated with HBF4*OEt2 (1 equiv.) at 0°C; mixt. was reacted for 10 min; washed (Et2O); dried (vac.); elem. anal.;

DOI:10.1021/om049178a

upstream raw materials:

sodium tetrahydroborate

[(C₅H₅)OsCl(NHC(C₆H₄Cl)CHC(CH₃)P(CH(CH₃)2)2)]