[Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(NCMe)(CO)(Cp)2]SO3CF3

Base Information

• Chemical Name: [Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(NCMe)(CO)(Cp)2]SO3CF3
• CAS No.: 306741-69-5
• Molecular Formula: CF₃O₃S*C₂₄H₂₅Fe₂N₂O₂
• Molecular Weight: 634.239
• Mol file: 306741-69-5.mol

Synonyms:

Chemical Property of [Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(NCMe)(CO)(Cp)2]SO3CF3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(NCMe)(CO)(Cp)2]SO3CF3

There total 1 articles about [Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(NCMe)(CO)(Cp)2]SO3CF3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(CO)2(Cp)2]SO3CF3 (306741-65-1) + acetonitrile (75-05-8,26809-02-9) → [Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(NCMe)(CO)(Cp)2]SO3CF3 (306741-69-5,511293-82-6)

Guidance literature:

With (CH₃)3NO; In acetonitrile; (N2); Schlenk technique; soln. of Fe complex in MeCN treated with anhydrous Me3NO; filtered on Celite pad; solvent removed; crystd. (CH2Cl2, pentane, -20°C); elem. anal.;

DOI:10.1016/S0022-328X(00)00337-5

Reference yield: 88.0%

[Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(NCMe)(CO)(Cp)2]SO3CF3 (306741-69-5,511293-82-6) + trimethylsilylacetylene (1066-54-2) → [Fe2(μ-σ:η3-C(SiMe3)CHCN(Me)(2,6-Me2C6H3))(mu.-CO)(CO)(Cp)2](SO3CF3)

Guidance literature:

In dichloromethane; byproducts: CH3CN; (N2); using Schlenk techniques; reflux of (Fe2(CO)2(NCMe)(Cp)2(CN(Me2C6H3)Me))(CF3SO3) and HCCSiMe3 in CH2Cl2 for 4 h; removal of solvent under reduced pressure, filtration on alumina pad with a mixt. of MeCN and THF (1:1) as eluent; crystn. at -20°C from THF soln. layered with diethyl ether; elem. anal.;

DOI:10.1021/om020923y

Reference yield: 88.0%

[Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(NCMe)(CO)(Cp)2]SO3CF3 (306741-69-5,511293-82-6) + propynoic acid methyl ester (922-67-8) → [Fe2(μ-η1:η3-Cγ(CO2Me)Cβ(H)CαN(Me)(C6H3-2,6-Me2))(μ-CO)(CO)(η5-cyclopentadienyl)2][SO3CF3]

Guidance literature:

In dichloromethane; under N2; Fe-contg. compd. (0.15 mmol) and HCCCO2Me (1.8 mmol) in CH2Cl2soln. were heated at refluxing temp. for 4 h; the solvent was removed under reduced pressure; the residue was washed with Et2O, dissolved in CH2Cl2 and filtered through celite; the solvent was removed in vac.; crystn. at -20°C from CH2Cl2 soln. layered with Et2O; E:Z ratio = 6; elem. anal.;

DOI:10.1016/j.jorganchem.2003.11.003

upstream raw materials:

[Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(CO)2(Cp)2]SO3CF3

acetonitrile

Downstream raw materials:

[Fe2(μ-CN(Me)Me2C6H3)(μ-H)(CO)2(Cp)2]

[Fe2(μ-CN(Me)Me2C6H3)(μ-CO)(CN)(CO)(Cp)2]

β-[Fe2(μ-CN(Me)(2,6-Me2C6H3))(μ-CO)(CO)(azido))(Cp)2]

α-[Fe2(μ-CN(Me)(2,6-Me2C6H3))(μ-CO)(CO)(azido))(Cp)2]