Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO)

Base Information

Chemical Name:Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO)
CAS No.:318502-24-8
Molecular Formula:C₂₇H₂₀N₂O₂PRh
Molecular Weight:538.347
Hs Code.:

Synonyms:

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Chemical Property of Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO)

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Technology Process of Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO)

There total 4 articles about Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

: 318502-22-6
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

: 318502-24-8
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO)

: 443288-90-2
[RhCl₃((C₆H₅)2PC₆H₄CHNNHCOC₆H₅)]

Guidance literature:: In toluene; under N2; soln. of rhodium complex in toluene heated under reflux for 2 h; solid filtered off, washed with toluene; dried in vac. (reichloro complex); remaining soln. concd. in vac. and cooled at -20°C for 1 week(carbonyl complex); elem. anal.;

Reference yield: 28.0%

: di(rhodium)tetracarbonyl dichloride

: 238433-65-3
2-(2-(diphenylphosphino)benzylidene)benzoic acid hydrazone

: 318502-24-8
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO)

: 443288-90-2
[RhCl₃((C₆H₅)2PC₆H₄CHNNHCOC₆H₅)]

Guidance literature:: In tetrahydrofuran; byproducts: CO, H2; under N2; Rh complex and ligand placed in refluxing THF, mixt. heated under reflux for 2 h; solid filtered off, washed with THF, dried in vac. (trichloro-complex); remaining soln. concd. in vac. and cooled at -20°C for 1 week (carbonyl complex);

Reference yield:

: 318502-22-6
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

: 318502-24-8
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO)

Guidance literature:: With NaOMe; In dichloromethane; under N2, MeONa was added to CH2Cl2 soln. of Rh-complex stirring for 3 hat room temp.; soln. was filtered, treated with Et2O, ppt. was collected, washed with Et2O, dried in vac.;
DOI:10.1021/om000562r