Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

Base Information

Chemical Name:Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl
CAS No.:318502-22-6
Molecular Formula:C₂₇H₂₁ClN₂O₂PRh
Molecular Weight:574.808
Hs Code.:

Synonyms:Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

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Chemical Property of Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

Chemical Property:

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Technology Process of Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

There total 3 articles about Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: di(rhodium)tetracarbonyl dichloride

: 238433-65-3
2-(2-(diphenylphosphino)benzylidene)benzoic acid hydrazone

: 318502-22-6
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

Guidance literature:: In diethyl ether; under N2, solid phosphine was added to Et2O soln. of Rh-complex in 2:1 molar ratio, stirring for 1 h at room temp.; solid was filtered off, washed with Et2O, dried in vac., elem. anal.;
DOI:10.1021/om000562r

Reference yield: 31.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 318502-24-8
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazonate)(CO)

: 318502-22-6
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

: 443288-89-9
[RhCl₂H((C₆H₅)2PC₆H₄CHNNHCOC₆H₅)(CO)]

: 443288-90-2
[RhCl₃((C₆H₅)2PC₆H₄CHNNHCOC₆H₅)]

Guidance literature:: In toluene; under N2; HCl bubbled through glass capillary into soln. of Rh complex in toluene; ppt. filtered off, repeatedly washed with toluene and then with water, dried in vac. (mixt. of complexes); crystn. of pure trichloro-complex from remaining soln. by slow evapn., ppt. filtered off, washed with tolueneand dried in vac.;

Reference yield:

: 238433-65-3
2-(2-(diphenylphosphino)benzylidene)benzoic acid hydrazone

: 318502-22-6
Rh(2-(diphenylphosphino)benzaldehyde benzoylhydrazone)(CO)Cl

Guidance literature:: Multi-step reaction with 2 steps

1: NaOMe / tetrahydrofuran

2: diethyl ether

With NaOMe; In tetrahydrofuran; diethyl ether;
DOI:10.1021/om000562r