mer,cis-[Re(NPh)Cl₂(bis[(2-diphenylphosphino)ethyl]amine)]Cl

Base Information

• Chemical Name: mer,cis-[Re(NPh)Cl₂(bis[(2-diphenylphosphino)ethyl]amine)]Cl
• CAS No.: 686740-76-1
• Molecular Formula: C₃₄H₃₄Cl₂N₂P₂Re*Cl
• Molecular Weight: 825.171

Synonyms:

Chemical Property of mer,cis-[Re(NPh)Cl₂(bis[(2-diphenylphosphino)ethyl]amine)]Cl

Chemical Property:

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Technology Process of mer,cis-[Re(NPh)Cl₂(bis[(2-diphenylphosphino)ethyl]amine)]Cl

There total 1 articles about mer,cis-[Re(NPh)Cl₂(bis[(2-diphenylphosphino)ethyl]amine)]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

trichloro(phenylimido)bis(triphenylphosphine)rhenium(V) + bis(2-(diphenylphosphino)ethyl)amine hydrochloride (66534-97-2) → mer-[Re(NPh)(OH)Cl(bis[(2-diphenylphosphino)ethyl]amine)]Cl (858127-43-2) + mer,cis-[Re(NPh)Cl2(bis[(2-diphenylphosphino)ethyl]amine)]Cl (686740-76-1)

Guidance literature:

With triethylamine; In dichloromethane; to suspn. Re complex in CH2Cl2 soln. aminodiphosphine hydrochloride and Et3N in CH2Cl2 was added dropwise, refluxed for 2 h and stirred overnight at room temp.; solvent was removed in vacuo, residue was washed with Et2O and water, and dried in vacuo, recrystn. from CH2Cl2-n-hexane(1:2); elem. anal.;

DOI:10.1021/ic048486y

Reference yield: 53.0%

mer,cis-[Re(NPh)Cl2(bis[(2-diphenylphosphino)ethyl]amine)]Cl (686740-76-1) + benzene-1,2-diol (120-80-9,19481-10-8,37349-32-9) → fac-[Re(NPh)(O,O-cat)(bis[(2-diphenylphosphino)ethyl]amine)]Cl*2H2O

Guidance literature:

With triethylamine; In dichloromethane; to soln. Re complex in CH2Cl2 catechol and Et3N were added at room temp.and stirred overnight at room temp.; solvent was removed, residue was treated with Et2O, ppt. was filtered and washed with n-hexane, Et2O, and water; elem. anal.;

DOI:10.1021/ic048486y

upstream raw materials:

bis(2-(diphenylphosphino)ethyl)amine hydrochloride

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