dodecacarbonyl[μ4-(η,η,eta.,η)(1-benzyloxy-2,5-undecadiyne)]tetracobalt

Base Information

• Chemical Name: dodecacarbonyl[μ4-(η,η,eta.,η)(1-benzyloxy-2,5-undecadiyne)]tetracobalt
• CAS No.: 700877-63-0
• Molecular Formula: C₃₀H₂₂Co₄O₁₃
• Molecular Weight: 826.47
• Mol file: 700877-63-0.mol

Synonyms:

Chemical Property of dodecacarbonyl[μ4-(η,η,eta.,η)(1-benzyloxy-2,5-undecadiyne)]tetracobalt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dodecacarbonyl[μ4-(η,η,eta.,η)(1-benzyloxy-2,5-undecadiyne)]tetracobalt

There total 1 articles about dodecacarbonyl[μ4-(η,η,eta.,η)(1-benzyloxy-2,5-undecadiyne)]tetracobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

dodecacarbonyl[μ4-(η,η,eta.,η)(1-benzyloxy-7-hydroxy-2,5-undecadiyne)]tetracobalt (700877-62-9) + triphenylstannane (892-20-6) → dodecacarbonyl[μ4-(η,η,eta.,η)(1-benzyloxy-2,5-undecadiyne)]tetracobalt (700877-63-0)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; (N2); BF3*Et2O (1 equiv.) was added to soln. of Co complex and Ph3SnH (1.5 equiv.) in CH2Cl2 at 5°C over 30 min; mixt. was stirred for 20h; quenched with H2O; chromd. (silica gel, petroleum ether/Et2O, 100/1);

DOI:10.1139/v03-209

upstream raw materials:

dodecacarbonyl[μ4-(η,η,eta.,η)(1-benzyloxy-7-hydroxy-2,5-undecadiyne)]tetracobalt

triphenylstannane