Technology Process of 3-Cyclohexen-1-one, 3-methyl-6-(1-methylethenyl)-, (6S)-
There total 15 articles about 3-Cyclohexen-1-one, 3-methyl-6-(1-methylethenyl)-, (6S)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
oxalyl dichloride; dimethyl sulfoxide; triethylamine;
In
dichloromethane;
at -60 - 20 ℃;
DOI:10.1081/SCC-120012982
- Guidance literature:
-
<5R-(trans)>-p-Mentha-1,8-dien-5-ol;
With
oxalyl dichloride; dimethyl sulfoxide;
In
dichloromethane;
at -60 ℃;
for 0.333333h;
With
triethylamine;
at -60 - 20 ℃;
for 1.16667h;
DOI:10.2174/1573406411309050013
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 70 percent / NBS / 24 h / Ambient temperature
2: 85 percent / LiAlH4 / diethyl ether / 5 h / Ambient temperature
3: 49 percent / Amberlyst 15 / ethanol / 6 h / Ambient temperature
4: 1.) DMSO, oxalyl chloride, 2.) Et3N / 1.) CH2Cl2, -60 deg C, 20 min, 2.) -60 deg C, 5 min; 25 deg C, 1 h
With
N-Bromosuccinimide; lithium aluminium tetrahydride; Amberlyst 15; oxalyl dichloride; dimethyl sulfoxide; triethylamine;
In
diethyl ether; ethanol;
DOI:10.1055/s-1988-27771
