((2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCl)2

Base Information

• Chemical Name: ((2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCl)2
• CAS No.: 700875-27-0
• Molecular Formula: C₅₈H₈₂Cl₂Fe₂N₄
• Molecular Weight: 1017.92
• Mol file: 700875-27-0.mol

Synonyms:

Chemical Property of ((2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCl)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCl)2

There total 1 articles about ((2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCl)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-pent-2-ene) lithium salt + iron(dichloride)*1.5(tetrahydrofuran) → ((2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCl)2 (700875-27-0) + FeCl2((CH(CH3)2)2C6H3NCCH3)2CH(1-)*Li(1+)*2C4H8O=FeCl2((CH(CH3)2)2C6H3NCCH3)2CHLi(C4H8O)2

Guidance literature:

In toluene; byproducts: LiCl; Schlenk flask was charged with Li-salt, Fe-compound and toluene, heated at 100°C for 12 h under N2; solvent was removed in vacuo, stirred with pentane, filtered, dried under vac., washed with pentane, Fe-complex was removed, stirred with Et2O for several h, crystd. from hot toluene; elem. anal.;

DOI:10.1021/ic035483x

Reference yield: 76.6%

((2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCl)2 (700875-27-0) + lithium 2,6-dimethylanilide → Fe((CH(CH3)2)2C6H3NCCH3)2CH(NH(CH3)2C6H3) (700875-35-0)

Guidance literature:

In pentane; Li-salt was added to soln. of Fe-complex in pentane, stirred for 12 h under N2; filtered, pumped to dryness, extd. with pentane, filtered, concd. at -35°C; elem. anal.;

DOI:10.1021/ic035483x

Reference yield: 67.0%

((2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCl)2 (700875-27-0) + diphenylphosphane (829-85-6) → [(HC(CMeNC6H3(i-Pr)2)2)Fe(μ2-PPh)]2 (882493-95-0)

Guidance literature:

With K/Na alloy; In toluene; byproducts: C6H6; under N2 atm. toluene was added to mixt. Fe complex and K/Na alloy at room temp., Ph2PH was added and stirred for 1 week; soln. was filtered, concd. in vacuo and kept at -35°C for week, ppt. was isolated; elem. anal.;

DOI:10.1039/b513892b

Downstream raw materials:

Fe((CH(CH₃)2)2C₆H₃NCCH₃)2CHOC(CH₃)3

Fe((CH(CH₃)2)2C₆H₃NCCH₃)2CH(NH(CH₃)2C₆H₃)

(2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCHMePh

(2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(phenethyl)