[η4-(3,4-dimethyl-1-phenylphosphole)tricarbonyliron] oxide

Base Information

• Chemical Name: [η4-(3,4-dimethyl-1-phenylphosphole)tricarbonyliron] oxide
• CAS No.: 91594-52-4
• Molecular Formula: C₁₅H₁₃FeO₄P
• Molecular Weight: 344.087
• Mol file: 91594-52-4.mol

Synonyms:

Chemical Property of [η4-(3,4-dimethyl-1-phenylphosphole)tricarbonyliron] oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [η4-(3,4-dimethyl-1-phenylphosphole)tricarbonyliron] oxide

There total 2 articles about [η4-(3,4-dimethyl-1-phenylphosphole)tricarbonyliron] oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[η4-(3,4-dimethyl-1-benzyl-1-phenylphospholium)tricarbonyliron] bromide (91582-77-3) + thallium (I) ethoxide (20398-06-5) → [η4-(3,4-dimethyl-1-phenylphosphole)tricarbonyliron] oxide (91594-52-4) + (CH2CCH3CCH3CHP(O)(C6H5)CH2C6H5)Fe(CO)3 (91594-49-9)

Guidance literature:

In ethanol; byproducts: CH2CCH3CCH3CHP(O)(C6H5)CH2C6H5; treating with ethanolic TlOEt; identified by chromy. and NMR spectra;

DOI:10.1016/0022-328X(84)80140-0

Reference yield:

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + η4-[3,4-dimethyl-1-phenylphosphole]tricarbonyliron (91594-51-3) → [η4-(3,4-dimethyl-1-phenylphosphole)tricarbonyliron] oxide (91594-52-4) + ((CH3)2C4H2P(C6H5))2(Fe(CO)2)2 (77611-23-5)

Guidance literature:

In not given; byproducts: Pd, CO; reaction was carried out in Ar in the presence of Pd complex at 25°C for 18 h; products were identified by IR and NMR spectra;

DOI:10.1016/0022-328X(84)80140-0

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

η4-[3,4-dimethyl-1-phenylphosphole]tricarbonyliron

[η4-(3,4-dimethyl-1-benzyl-1-phenylphospholium)tricarbonyliron] bromide

thallium (I) ethoxide