Technology Process of η4-[3,4-dimethyl-1-phenylphosphole]tricarbonyliron
There total 1 articles about η4-[3,4-dimethyl-1-phenylphosphole]tricarbonyliron which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
ammonium hydroxide; aluminium trichloride; ammonium chloride;
In
chloroform; water;
Fe complex in CHCl3 adding to AlCl3 soln. in CHCl3 under Ar, refluxing for 3.5 h, cooling to room temp., pouring into water satd. with NH4Cl, aq. phase treating with 28% NH4OH, extg. with CH2Cl2, washing with water to neutral pH, concg., drying on MgSO4; identified chromatografically by comparison with authentic sample, IR and NMR spectra;
DOI:10.1016/0022-328X(84)80140-0
- Guidance literature:
-
With
tetrahydrofuran;
In
tetrahydrofuran;
Irradiation (UV/VIS); W(CO)5(THF) generating from W(CO)6 by UV irradiating in THF under Ar, then Fe complex adding, stirring for 30 min at room temp. and evapg.; identified by IR. NMR and mass spectra;
DOI:10.1016/0022-328X(84)80140-0
- Guidance literature:
-
With
triethylamine;
In
diethyl ether; water;
byproducts: (CH3CH2)3NHCl; Fe complex stiriing with an excess of benzoyl chloride in ether under Ar for 30 min at room temp., water adding, stirring additional several hs., white ppt. treating with hot benzene, org. phase cooling, yellow ppt.collecting; identified by IR, NMR and mass spectra;
DOI:10.1016/0022-328X(84)80140-0
