(η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2)

Base Information

• Chemical Name: (η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2)
• CAS No.: 1364681-47-9
• Molecular Formula: C₃₄H₃₁Fe₂P
• Molecular Weight: 582.288
• Mol file: 1364681-47-9.mol

Synonyms:

Chemical Property of (η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2)

There total 1 articles about (η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

1′,1′′′-dibromobiferrocene + bis(o-tolyl)chlorophosphine (36042-94-1) → (η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2) (1364681-47-9)

Guidance literature:

With n-butyllithium; ethanol; In tetrahydrofuran; hexane; under N2 or Ar; BuLi in hexane added (-70°C) to Fe complex in THF; stirred (60 min); phosphine (1 equiv.) added; stirred (ambient temp.,12 h); chromd. (alumina, toluene-hexane); dried; dissolved in THF; BuLi added (-70°C); stirred(30 min); EtOH added; stirred at ambient temp. for 1 h; volatiles evapd.; purifiedby column chromy. (alumina, toluene-n-hexane 1:2); volatiles removed; e lem. anal.;

DOI:10.1021/om201220w

Reference yield: 89.0%

selenium (7782-49-2) + (η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2) (1364681-47-9) → (η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2Se) (1364681-93-5)

Guidance literature:

In toluene; under N2 or Ar; Se (1.2 equiv.) added to toluene soln. of Fe complex; stirred at 100°C for 5 h; cooled to ambient temp.; filtered through Celite; volatiles removed from filtrate under vac.; elem. anal.;

DOI:10.1021/om201220w

Reference yield: 81.6%

bis(diethyl sulfide)palladium dichloride (27199-13-9,14873-91-7,55528-77-3) + (η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2) (1364681-47-9) → trans-[Pd((η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2))2Cl2]

Guidance literature:

In dichloromethane; under N2 or Ar; Pd complex added to CH2Cl2 soln. of Fe complex; stirred at 25°C for 5 h; reduced in vol.; n-hexane added; ppt. washed with n-hexane; dried under oil pump vac.; elem. anal.;

DOI:10.1021/om201220w

upstream raw materials:

bis(o-tolyl)chlorophosphine

Downstream raw materials:

(η5-C5H5)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4P(o-tolyl)2Se)