36042-94-1Relevant articles and documents
SYNTHESIS AND PHYSICAL PROPERTIES OF CHLORODI(o-TOLYL)PHOSPHINE, LITHIUM DI(o-TOLYL)PHOSHIDE AND THE DIPHOSPHINE SERIES (o-TOLYL)2P(CH2)NP(o-TOYLYL) (n =1-4, 6,8)
Clark, Peter W.,Mulraney, Bernard J.
, p. 51 - 59 (1981)
The starting material chlorodi(o-tolyl)phosphine has been prepared by the reaction of phosphorus trichloride and the Grignard of o-chlorotoluene.The intermediate lithium di(o-tolyl)phosphide was obtained by the direct reaction of lithium metal and chlorod
Palladium-Catalyzed Cascade C?O Cleavage and C?H Alkenylation of Phosphinyl Allenes: An Expeditious Approach to 3-Alkenyl Benzo[b]phosphole Oxides
Liu, Teng,Sun, Xue,Wu, Lei
supporting information, p. 2005 - 2012 (2018/03/27)
A phosphine oxide-directed intramolecular cyclization of phosphinyl allenes is established for the first time. The palladium-catalyzed intramolecular cyclization provides an unprecedented cascade C?O cleavage and direct C?H alkenylation toward novel 3-alk
TETRAMERISATION OF ETHYLENE
-
, (2014/12/09)
A process for the tetramerisation of ethylene includes contacting ethylene with a catalyst under ethylene oligomerisation conditions. The catalyst comprises a source of chromium, a ligating compound, and an activator. The ligating compound includes a phosphine that forms part of a cyclic structure.