1-(Phenylthio)-9-phenyldibenzothiophene

Base Information

• Chemical Name: 1-(Phenylthio)-9-phenyldibenzothiophene
• CAS No.: 158637-52-6
• Molecular Formula: C₂₄H₁₆S₂
• Molecular Weight: 368.523
• Mol file: 158637-52-6.mol

Synonyms:

Chemical Property of 1-(Phenylthio)-9-phenyldibenzothiophene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(Phenylthio)-9-phenyldibenzothiophene

There total 3 articles about 1-(Phenylthio)-9-phenyldibenzothiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

1-(Phenylsulfinyl)-9-(phenylthio)dibenzothiophene (140868-26-4) + phenylmagnesium bromide (100-58-3) → 1-(Phenylthio)-9-phenyldibenzothiophene (158637-52-6)

Guidance literature:

With copper dichloride; In tetrahydrofuran;

DOI:10.1016/0040-4039(94)02461-J

Reference yield:

1,9-bis(phenylthio)dibenzothiophene (135489-49-5) → 1-(Phenylthio)-9-phenyldibenzothiophene (158637-52-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 74 percent / m-CPBA / CH₂Cl₂ / 12 h / -20 °C

2: 1.) PhMgBr, 2.) CuCl₂ / 1.) THF, 5 h, 2.) 12 h

With phenylmagnesium bromide; 3-chloro-benzenecarboperoxoic acid; copper dichloride; In dichloromethane;

DOI:10.1021/jo00102a043

Reference yield:

1-(Phenylsulfinyl)-9-(phenylthio)dibenzothiophene (140868-26-4) → 1-(Phenylthio)-9-phenyldibenzothiophene (158637-52-6)

Guidance literature:

With phenylmagnesium bromide; copper dichloride; Yield given. Multistep reaction; 1.) THF, 5 h, 2.) 12 h;

DOI:10.1021/jo00102a043

upstream raw materials:

1-(Phenylsulfinyl)-9-(phenylthio)dibenzothiophene

phenylmagnesium bromide

1,9-bis(phenylthio)dibenzothiophene