Ir(CH₃)(CO)I₂((C₆H₅)2PC₂H₄P(C₆H₅)2)

Base Information

• Chemical Name: Ir(CH₃)(CO)I₂((C₆H₅)2PC₂H₄P(C₆H₅)2)
• CAS No.: 175231-03-5
• Molecular Formula: C₂₈H₂₇I₂IrOP₂
• Molecular Weight: 887.498
• Mol file: 175231-03-5.mol

Synonyms:

Chemical Property of Ir(CH₃)(CO)I₂((C₆H₅)2PC₂H₄P(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ir(CH₃)(CO)I₂((C₆H₅)2PC₂H₄P(C₆H₅)2)

There total 1 articles about Ir(CH₃)(CO)I₂((C₆H₅)2PC₂H₄P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

IrI(CO)(1,2-bis(diphenylphosphino)ethane) (85421-68-7) → Ir(CH3)(CO)I2((C6H5)2PC2H4P(C6H5)2) (175231-03-5)

Guidance literature:

With methyl iodide; In dichloromethane; oxidative addn. of excess org. ligand;

DOI:10.1016/0020-1693(95)04527-9

Reference yield: 80.0%

silver(I) hexafluorophosphate (26042-63-7) + Ir(CH3)(CO)I2((C6H5)2PC2H4P(C6H5)2) (175231-03-5) → Ir(C(O)CH3)(CH3CN)3((C6H5)2PCH2)2(2+)*2PF6(1-)=[Ir(C(O)CH3)(CH3CN)3((C6H5)2PCH2)2](PF6)2

Guidance literature:

In acetonitrile; byproducts: AgI; Ag-salt soln. addn. to Ir-compd. soln., stirring 3 h in dark, reaction mixt. decanting (AgI removal), soln. passing through glass wool column, filtrate concn., pptn. on diethyl ether addn.; solid recrystn. from acetonitrile/diethyl ether; elem. anal.;

DOI:10.1016/0020-1693(95)04527-9

Reference yield:

Ir(CH3)(CO)I2((C6H5)2PC2H4P(C6H5)2) (175231-03-5) → Ir(2)H(CO)(SO3CF3)2((C6H5)2PC2H4P(C6H5)2)

Guidance literature:

Multi-step reaction with 3 steps

1: dichloromethane

2: H₂ / dichloromethane

3: dichloromethane-d2

With H₂; In dichloromethane; dichloromethane-d2;

DOI:10.1016/0020-1693(95)04527-9

upstream raw materials:

IrI(CO)(1,2-bis(diphenylphosphino)ethane)

Downstream raw materials:

IrH(CO)(SO₃CF₃)2((C₆H₅)2PC₂H₄P(C₆H₅)2)