[Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4

Base Information

• Chemical Name: [Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4
• CAS No.: 721399-48-0
• Molecular Formula: BF₄*C₂₉H₂₈N₂PRu
• Molecular Weight: 623.403
• Mol file: 721399-48-0.mol

Synonyms:

Chemical Property of [Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4

There total 1 articles about [Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II) + C5H5CH2CHC6H5P(C6H5)2 + potassium tetrafluoroborate (14075-53-7) → [Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4 (721399-48-0)

Guidance literature:

With Li₂CO₃; In ethanol; acetonitrile; Ru-complex, Li2CO3 and KBF4 were mixed with MeCN-EtOH, ligand in MeCN was added, stirred under reflux for 8 h under N2; filtered through alumina, slow crystn. at -35°C;

DOI:10.1016/S0020-1693(02)01502-5

Reference yield: 99.0%

[Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4 (721399-48-0) + tris(1-methylethyl)phosphine (6476-36-4) → [(η5-C5H4-CH2CHPhPPh2-κP)Ru(MeCN)(PiPr3)]BF4

Guidance literature:

In dichloromethane; Ru-complex in CH2Cl2 was mixed with ligand, stirred at room temp. under N2; concd., Et2O was added dropwise, filtered; elem. anal.;

DOI:10.1016/S0020-1693(02)01502-5

Reference yield: 99.0%

[Ru(η5-C5H4CH2CH(Ph)-κ1P-PPh2)(acetonitrile)2]BF4 (721399-48-0) + tricyclohexylphosphine (2622-14-2) → [(η5-C5H4-CH2CHPhPPh2-κP)Ru(MeCN)(PCy3)]BF4

Guidance literature:

In dichloromethane; Ru-complex in CH2Cl2 was mixed with ligand, stirred at room temp. under N2; concd., Et2O was added dropwise, filtered; elem. anal.;

DOI:10.1016/S0020-1693(02)01502-5

upstream raw materials:

potassium tetrafluoroborate

Refernces