Ni(P(C₆H₅)3)2CH₂SCH₃Cl

Base Information

Chemical Name:Ni(P(C₆H₅)3)2CH₂SCH₃Cl
CAS No.:96348-98-0
Molecular Formula:C₃₈H₃₅ClNiP₂S
Molecular Weight:679.852
Hs Code.:

Ni(P(C<sub>6</sub>H<sub>5</sub>)3)2CH<sub>2</sub>SCH<sub>3</sub>Cl

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ni(P(C₆H₅)3)2CH₂SCH₃Cl

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Technology Process of Ni(P(C₆H₅)3)2CH₂SCH₃Cl

There total 2 articles about Ni(P(C₆H₅)3)2CH₂SCH₃Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 14264-16-5,53996-95-5,62075-39-2,39716-73-9
bis(triphenylphosphine)nickel(II) chloride

: 10415-47-1
(methylthio)methyllithium

: 96348-98-0
Ni(P(C₆H₅)3)2CH₂SCH₃Cl

Guidance literature:: In tetrahydrofuran; hexane; byproducts: LiCl; suspn. of complex in THF at 0°C was treated with soln. of 1 equiv of LiCH2SCH3 in hexane over 1-2 min, warmed to room temp., stirred overnight (N2); solid was dried under vac.;
DOI:10.1021/om00126a007

Reference yield:

: 23777-40-4
bis(triphenylphosphine)ethylenenickel⁽⁰⁾

: 2373-51-5
chloro-methylsulfanyl-methane

: 96348-98-0
Ni(P(C₆H₅)3)2CH₂SCH₃Cl

Guidance literature:: With triphenyl phosphine; In diethyl ether; suspn. of complex in ether at 0°C was treated dropwise with ClCH2SCH3, 1 equiv of PPh3 was incorporated, mixt. was warmed to room temp.;(N2);
DOI:10.1021/om00126a007

Reference yield: 78.0%

: ammonium hexafluorophosphate

: 96348-98-0
Ni(P(C₆H₅)3)2CH₂SCH₃Cl

: 96348-86-6
Ni(P(C₆H₅)3)2CH₂SCH₃⁽¹⁺⁾*PF₆^(1-)=Ni(P(C₆H₅)3)2CH₂SCH₃PF₆

Guidance literature:: In acetone; acetone soln. of complex was treated with acetone soln. of NH4PF6 (N2); ppt. was removed, soln. was concd. under vac., solid was washed with ether and dried under vac.; elem anal.;
DOI:10.1021/om00126a007