1,1-diphenylstannacycloheptane

Base Information

• Chemical Name: 1,1-diphenylstannacycloheptane
• CAS No.: 20210-05-3
• Molecular Formula: C₁₈H₂₂Sn
• Molecular Weight: 357.083
• Mol file: 20210-05-3.mol

Synonyms:

Chemical Property of 1,1-diphenylstannacycloheptane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1-diphenylstannacycloheptane

There total 2 articles about 1,1-diphenylstannacycloheptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

diphenyltin(IV) dichloride (1135-99-5) + hexane-1,6-diyl-bis-magnesium bromide (17036-36-1) → 1,1-diphenylstannacycloheptane (20210-05-3)

Guidance literature:

In tetrahydrofuran; diethyl ether; under N2; to a soln. of the Grignard reagent in ether was quickly added a soln. ofPh2SnCl2 in THF, refluxed for 12 h; cooled to room temp., addn. of water, filtered, washed with pentane, filtrate and washings were combined, evapd., taken up in hexane, dried (Na2SO4), concd., column separation;

DOI:10.1021/om00036a030

Reference yield:

→ 1,1-diphenylstannacycloheptane (20210-05-3)

Guidance literature:

Aus BrMg-(CH2)6-MgBr u. Phe2-SnX2 in Diethylether;

upstream raw materials:

diphenyltin(IV) dichloride

hexane-1,6-diyl-bis-magnesium bromide