(C₅H₅)(CO)(P(C₂H₅)3)FeC₆H₅

Base Information

• Chemical Name: (C₅H₅)(CO)(P(C₂H₅)3)FeC₆H₅
• CAS No.: 117094-52-7
• Molecular Formula: C₁₈H₂₅FeOP
• Molecular Weight: 344.217
• Mol file: 117094-52-7.mol

Synonyms:

Chemical Property of (C₅H₅)(CO)(P(C₂H₅)3)FeC₆H₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₅H₅)(CO)(P(C₂H₅)3)FeC₆H₅

There total 1 articles about (C₅H₅)(CO)(P(C₂H₅)3)FeC₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

(cyclopentadienyl)Fe(CO)2COPh + triethylphosphine (554-70-1) → (C5H5)(CO)(P(C2H5)3)FeC6H5 (117094-52-7) + (C5H5)(CO)(P(C2H5)3)FeCOC6H5 (117094-53-8)

Guidance literature:

In benzene; Irradiation (UV/VIS); photolysis with a sunlamp for 1 h with a nitrogen purge through the soln.; removal of solvent in vacuo, chromy. on alumina: Cp(CO)(PEt3)FeC6H5 elutes first with 15:1 hexanes/ethyl acetate, then Cp(CO)(PEt3)FeCOC6H5 elutes with a solvent ratio of 5:1; elem. anal.;

DOI:10.1021/ja00184a025

upstream raw materials:

triethylphosphine