Pt(P(C₆H₅)3)2(O₂C(CH₂CO₂CH₃)2O)

Base Information

• Chemical Name: Pt(P(C₆H₅)3)2(O₂C(CH₂CO₂CH₃)2O)
• CAS No.: 69503-11-3
• Molecular Formula: C₄₃H₄₀O₇P₂Pt
• Molecular Weight: 925.814
• Mol file: 69503-11-3.mol

Synonyms:

Chemical Property of Pt(P(C₆H₅)3)2(O₂C(CH₂CO₂CH₃)2O)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Pt(P(C₆H₅)3)2(O₂C(CH₂CO₂CH₃)2O)

There total 2 articles about Pt(P(C₆H₅)3)2(O₂C(CH₂CO₂CH₃)2O) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

3-oxopentanedioic acid dimethyl ester (1830-54-2) + tetrakis(triphenylphosphine)platinum (14221-02-4) → [1,3-bis(methoxycarbonyl)-2-oxopropane-1,3-diyl]bis(triphenylphosphine)platinum + Pt(P(C6H5)3)2(O2C(CH2CO2CH3)2O) (69503-11-3)

Guidance literature:

In diethyl ether; an excess of 3-oxopentanedioate and Pt complex stirring in Et2O in openflask for 24 h, white powder filtering off, the remaining mixt. stirring for a total 12 d, resulting white solid washing with Et2O and drying in vacuo; identified by elem. anal., IR and NMR spectra;

DOI:10.1039/DT9840001993

Reference yield: 68.0%

3-oxopentanedioic acid dimethyl ester (1830-54-2) + dioxygenbis(triphenylphosphine)platinum(0) (29894-57-3) → Pt(P(C6H5)3)2(O2C(CH2CO2CH3)2O) (69503-11-3)

Guidance literature:

In diethyl ether; an excess of 3-oxopentanedioate and Pt complex stirring in Et2O for 1 h, white powder filtering off, washing with Et2O and drying in vacuo; identified by elem. anal., IR and NMR spectra;

DOI:10.1039/DT9840001993

Reference yield: 84.0%

Pt(P(C6H5)3)2(O2C(CH2CO2CH3)2O) (69503-11-3) + Hexafluoroacetone (684-16-2) → Pt(P(C6H5)3)2(O2C(CF3)2O) (31203-97-1)

Guidance literature:

In diethyl ether; an excess of hexafluoroacetone condensing at -196°C onto a susp.of Pt complex in Et2O contained in a Carius tube, the tube sealing, shaking at room temp. for 7 d, cooling, opening, volatiles removing, white solid filtering off, washing with Et2O; purified by recrystallization from CH2Cl2-light petroleum; identified by elem. anal.;

DOI:10.1039/DT9840001993

upstream raw materials:

3-oxopentanedioic acid dimethyl ester

dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

tetrakis(triphenylphosphine)platinum

Downstream raw materials:

Pt(P(C₆H₅)3)2(O₂C(CF₃)2O)

Refernces