DL-2,3,4,5,6-penta-O-benzyl-myo-inositol 1-<(S)-3,4-(isopropylidenedioxy)butanesulfonate>

Base Information

Chemical Name:DL-2,3,4,5,6-penta-O-benzyl-myo-inositol 1-<(S)-3,4-(isopropylidenedioxy)butanesulfonate>
CAS No.:134275-53-9
Molecular Formula:C₄₈H₅₄O₁₀S
Molecular Weight:823.017
Hs Code.:

Synonyms:

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Chemical Property of DL-2,3,4,5,6-penta-O-benzyl-myo-inositol 1-<(S)-3,4-(isopropylidenedioxy)butanesulfonate>

Chemical Property:

Purity/Quality:

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Technology Process of DL-2,3,4,5,6-penta-O-benzyl-myo-inositol 1-<(S)-3,4-(isopropylidenedioxy)butanesulfonate>

There total 17 articles about DL-2,3,4,5,6-penta-O-benzyl-myo-inositol 1-<(S)-3,4-(isopropylidenedioxy)butanesulfonate> which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6763-47-9,1251832-23-1
rac-1,2-O-cyclohexylidene-myo-inositol

: 134275-53-9,141899-73-2,141899-78-7
2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-ethanesulfonic acid (1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: NaH / dimethylformamide

2: 71 percent / aq. HOAc

3: 1) Bu₂SnO, 2) CsF / 1) MeOH, 2) DMF

4: 88 percent / NaH / dimethylformamide

5: 95 percent / p-TsOH / Pd-C / methanol; H₂O / Heating

6: 85 percent / pyridine / CH₂Cl₂

7: 1) BuLi / 1) n-hexane, THF, -78 deg C, 2) THF, a) 1 h, -78 deg C, b) 2 h, r.t.

With pyridine; n-butyllithium; sodium hydride; di(n-butyl)tin oxide; toluene-4-sulfonic acid; acetic acid; cesium fluoride; palladium on activated charcoal; In methanol; dichloromethane; water; N,N-dimethyl-formamide;

Reference yield:

: 6763-47-9,1251832-23-1
rac-1,2-O-cyclohexylidene-myo-inositol

: 134275-53-9,141899-73-2,141899-78-7
2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-ethanesulfonic acid (1S,2S,3R,4S,5S,6S)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: NaH / dimethylformamide

2: 71 percent / aq. HOAc

3: 1) Bu₂SnO, 2) CsF / 1) MeOH, 2) DMF

4: 88 percent / NaH / dimethylformamide

5: 95 percent / p-TsOH / Pd-C / methanol; H₂O / Heating

6: 85 percent / pyridine / CH₂Cl₂

7: 1) BuLi / 1) n-hexane, THF, -78 deg C, 2) THF, a) 1 h, -78 deg C, b) 2 h, r.t.

With pyridine; n-butyllithium; sodium hydride; di(n-butyl)tin oxide; toluene-4-sulfonic acid; acetic acid; cesium fluoride; palladium on activated charcoal; In methanol; dichloromethane; water; N,N-dimethyl-formamide;

Reference yield:

: 6691-27-6,57029-85-3,57029-86-4,130324-54-8
(+/-)-cis-1,2-O-cyclohexylidene-3,4,5,6-tetrakis-O-benzyl myo-inositol

: 134275-53-9,141899-73-2,141899-78-7
2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-ethanesulfonic acid (1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 71 percent / aq. HOAc

2: 1) Bu₂SnO, 2) CsF / 1) MeOH, 2) DMF

3: 88 percent / NaH / dimethylformamide

4: 95 percent / p-TsOH / Pd-C / methanol; H₂O / Heating

5: 85 percent / pyridine / CH₂Cl₂

6: 1) BuLi / 1) n-hexane, THF, -78 deg C, 2) THF, a) 1 h, -78 deg C, b) 2 h, r.t.

With pyridine; n-butyllithium; sodium hydride; di(n-butyl)tin oxide; toluene-4-sulfonic acid; acetic acid; cesium fluoride; palladium on activated charcoal; In methanol; dichloromethane; water; N,N-dimethyl-formamide;