[o-(CH=N-2,6-iPr₂C₆H₃)C₆H₄]SbCl₂

Base Information

• Chemical Name: [o-(CH=N-2,6-iPr₂C₆H₃)C₆H₄]SbCl₂
• CAS No.: 1310554-25-6
• Molecular Formula: C₁₉H₂₂Cl₂NSb
• Molecular Weight: 457.046

Synonyms:

Chemical Property of [o-(CH=N-2,6-iPr₂C₆H₃)C₆H₄]SbCl₂

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Technology Process of [o-(CH=N-2,6-iPr₂C₆H₃)C₆H₄]SbCl₂

There total 1 articles about [o-(CH=N-2,6-iPr₂C₆H₃)C₆H₄]SbCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

o-C6H4(CHNC6H3iPr2-2,6)Li + antimony(III) chloride (10025-91-9) → [o-(CH=N-2,6-iPr2C6H3)C6H4]SbCl2 (1310554-25-6)

Guidance literature:

In diethyl ether; hexane; Schlenk techniques used under Ar, Et2O soln. of SbCl3 (13 mmol) added toEt2O/C6H14 suspn. of LiC6H4CHNC6H3iPr2 (in situ prepd. from C6H14 soln. of nBuLi (13 mmol), Et2O soln. of BrC6H4CHNC6H3iPr2 (13 mmol)) at -40.d egree.C, stirred for 3h at room temp.; volume reduced, insoluble material filtered off, washed with hexane at -30°C, solid extd. by CH2Cl2, ext. evapd., recrystd. from hot hexane; elem. anal., XRD;

DOI:10.1002/ejic.201100010

Reference yield: 83.0%

sulfuryl dichloride (7791-25-5) + [o-(CH=N-2,6-iPr2C6H3)C6H4]SbCl2 (1310554-25-6) → [2-(CH=N-2',6'-iPr2C6H3)C6H4]SbCl4 (1515648-10-8)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃; for 1h;

DOI:10.1039/c3dt51733k

Reference yield: 45.0%

[o-(CH=N-2,6-iPr2C6H3)C6H4]SbCl2 (1310554-25-6) → ([o-C6H4(CHNC6H3iPr2-2,6)]Sb)4

Guidance literature:

With K[B(sBu)3H]; In tetrahydrofuran; byproducts: hydrogen, B(sBu)3; Schlenk techniques used under Ar, 1M THF soln. of K(B(sBu)3H) (3.7 mmol)added with stirring to THF soln. of (C6H4CHNC6H3iPr2)SbCl2 (1.84 mmol) at room temp., stirred for 1 h at room temp.; evapd. in vac., washed with hexane, solid extd. with toluene, evapd., recrystd. from toluene/hexane; elem. anal., XRD;

DOI:10.1002/ejic.201100010

upstream raw materials:

antimony(III) chloride

Downstream raw materials:

[2-(CH=N-2',6'-iPr₂C₆H₃)C₆H₄]SbCl₄

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