anti-2-(4-biphenyl)cyclohexanone oxime

Base Information

• Chemical Name: anti-2-(4-biphenyl)cyclohexanone oxime
• CAS No.: 132272-27-6
• Molecular Formula: C₁₈H₁₉NO
• Molecular Weight: 265.355
• Mol file: 132272-27-6.mol

Synonyms:

Chemical Property of anti-2-(4-biphenyl)cyclohexanone oxime

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of anti-2-(4-biphenyl)cyclohexanone oxime

There total 3 articles about anti-2-(4-biphenyl)cyclohexanone oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1-nitrocyclohexene (2562-37-0) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 3,4-tetramethylene-4H-1,2-benzoxazine (127383-36-2) + anti-2-(4-biphenyl)cyclohexanone oxime (132272-27-6) + syn-2-(2-biphenyl)cyclohexanone oxime (132272-26-5) + anti-2-(2-biphenyl)cyclohexanone oxime (132272-25-4)

Guidance literature:

With trifluorormethanesulfonic acid; at 18 ℃; for 20h; Further byproducts given. Yields of byproduct given;

DOI:10.1016/S0040-4020(01)89066-9

Reference yield:

1-nitrocyclohexene (2562-37-0) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → anti-2-(4-biphenyl)cyclohexanone oxime (132272-27-6) + syn-2-(2-biphenyl)cyclohexanone oxime (132272-26-5) + anti-2-(2-biphenyl)cyclohexanone oxime (132272-25-4)

Guidance literature:

With trifluorormethanesulfonic acid; at 18 ℃; for 20h; Yield given. Further byproducts given. Yields of byproduct given;

DOI:10.1016/S0040-4020(01)89066-9

Reference yield:

1-nitrocyclohexene (2562-37-0) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → syn-2-(4-biphenyl)cyclohexanone oxime (132272-28-7) + anti-2-(4-biphenyl)cyclohexanone oxime (132272-27-6) + syn-2-(2-biphenyl)cyclohexanone oxime (132272-26-5) + anti-2-(2-biphenyl)cyclohexanone oxime (132272-25-4)

Guidance literature:

With trifluorormethanesulfonic acid; at 18 ℃; for 20h; Yield given. Further byproducts given. Yields of byproduct given;

DOI:10.1016/S0040-4020(01)89066-9

upstream raw materials:

1-nitrocyclohexene

benzene