<3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine

Base Information

Chemical Name:<3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine
CAS No.:165674-27-1
Molecular Formula:C₂₇H₃₅NO₉
Molecular Weight:517.576
Hs Code.:

<3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine

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Chemical Property of <3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine

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Technology Process of <3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine

There total 5 articles about <3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17680-04-5
(3,4-methylenedioxy)phenylmagnesium bromide

: 165674-27-1
<3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / tetrahydrofuran / 3.5 h / -78 - -10 °C

2: DMAP / 1,2-dichloro-ethane / 24 h / Heating

3: Bu₃SnH, AIBN / toluene / Heating

With dmap; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In tetrahydrofuran; 1,2-dichloro-ethane; toluene;
DOI:10.1021/jo9902042

Reference yield:

: (4S,5S)-5-((1R,2S)-1,2-Bis-methoxymethoxy-3-oxo-propyl)-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde O-benzyl-oxime

: 165674-27-1
<3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / tetrahydrofuran / 3.5 h / -78 - -10 °C

2: DMAP / 1,2-dichloro-ethane / 24 h / Heating

3: Bu₃SnH, AIBN / toluene / Heating

With dmap; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In tetrahydrofuran; 1,2-dichloro-ethane; toluene;
DOI:10.1021/jo9902042

Reference yield:

: (3S,2R)-3-<(5S,4R)-5-<(1Z/E)-2-aza-2-(phenylmethoxy)vinyl>-2,2-dimethyl(1,3-dioxolan-4-yl)>-2,3-bis(methoxymethyl)propan-1-ol

: 165674-27-1
<3-(2H-benzo<3,4-d>1,3-dioxolan-5-yl)-(1S,3S,5S,2R,4R,6R)-4,5-bis(methoxymethoxy)-8,8-dimethyl-7,9-dioxabicyclo<4.3.0>non-2-yl>(phenylmethoxy)amine

Guidance literature:: Multi-step reaction with 4 steps

1: 87 percent / NMO, tetrapropylammonium perruthenate / CH₂Cl₂ / 0.5 h / Ambient temperature

2: 82 percent / tetrahydrofuran / 3.5 h / -78 - -10 °C

3: DMAP / 1,2-dichloro-ethane / 24 h / Heating

4: Bu₃SnH, AIBN / toluene / Heating

With dmap; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane; toluene;
DOI:10.1021/jo9902042