2-Buten-1-ol, 3-(tributylstannyl)-, (E)-

Base Information

• Chemical Name: 2-Buten-1-ol, 3-(tributylstannyl)-, (E)-
• CAS No.: 124607-17-6
• Molecular Formula: C₁₆H₃₄OSn
• Molecular Weight: 361.155
• Mol file: 124607-17-6.mol

Synonyms:

Chemical Property of 2-Buten-1-ol, 3-(tributylstannyl)-, (E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Buten-1-ol, 3-(tributylstannyl)-, (E)-

There total 1 articles about 2-Buten-1-ol, 3-(tributylstannyl)-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

tri-n-butyl-tin hydride (688-73-3) + 4-(p-methoxybenzyloxy)-1-hydroxy-2-butyne (145222-40-8) → 3-(tributylstannyl)but-2-en-1-ol (850354-34-6,121882-41-5,124607-17-6) + HOCH2CHC(Sn(C4H9)3)CH2O(CH2C6H4OCH3) (145222-54-4,145222-55-5) + CH3C(Sn(C4H9)3)CHCH2O(CH2C6H4OCH3) (145222-51-1,145222-50-0) + 4-Methoxybenzyl alcohol (105-13-5)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); In toluene; AIBN and HSnBu3 added to the soln. of mono ether, stirred for 3 h at reflux; extracted with Et2O, chromy. ( silica gel); elem. anal.;

Reference yield: 100.0%

(2E)-3-methyl-3-tributylstannylprop-2-en-1-ol (121882-41-5,124607-17-6,850354-34-6) + (E)-2-(2,6,6-trimethylcyclohexen-1-yl)ethenyl nonafluorobutanesulfonate (475673-41-7) → (2E,4E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexenyl)-2,4-pentadien-1-ol (3917-39-3)

Guidance literature:

With triphenyl-arsane; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In N,N-dimethyl-formamide; at 20 ℃; for 2h;

DOI:10.1055/s-2002-32602

Reference yield: 100.0%

(E,SS)-2-phenyl-1-(p-tolylsulfinyl)-1-iodoethane (1045345-99-0) + 3-(tributylstannyl)but-2-en-1-ol (850354-34-6,121882-41-5,124607-17-6) → (-)-(S)-2-(E)-4-(Z)-3-methyl-5-phenyl-4-(p-tolylsulfinyl)penta-2,4-dien-1-ol (1211944-97-6)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenyl-arsane; 2,6-di-tert-butyl-4-methyl-phenol; In tetrahydrofuran; at 20 ℃; for 20h; Inert atmosphere;

DOI:10.1021/jo9024489

upstream raw materials:

tri-n-butyl-tin hydride

4-(p-methoxybenzyloxy)-1-hydroxy-2-butyne

Downstream raw materials:

(Z)-3-[4-(Methoxycarbonyl)phenyl]but-2-en-1-ol

(2Z,4E)-3-methyl-5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-dienol