[2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide)

Base Information

Chemical Name:[2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide)
CAS No.:445467-62-9
Molecular Formula:C₄₀H₃₂O₆P₂
Molecular Weight:670.638
Hs Code.:

Synonyms:

Suppliers and Price of [2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide)

There total 5 articles about [2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 445380-60-9
(2,3-dihydro-1,4-benzodioxin-6-yl)phospane oxide

: 503538-67-8,445380-62-1,445467-62-9
[2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide)

Guidance literature:: (2,3-dihydro-1,4-benzodioxin-6-yl)phospane oxide; With tert.-butyl lithium; In tetrahydrofuran; at -100 - -70 ℃;

With iron(III) chloride; at -70 - 20 ℃;
DOI:10.1016/S0040-4039(02)02637-0

Reference yield:

: 493-09-4
benzo-1,4-dioxane

: 503538-67-8,445380-62-1,445467-62-9
[2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide)

Guidance literature:: Multi-step reaction with 5 steps

1.1: 100 percent / NBS / dimethylformamide / 24 h / 20 °C

2.1: n-BuLi / tetrahydrofuran; hexane / 1.17 h / -78 °C

2.2: tetrahydrofuran; hexane / -70 - 0 °C

3.1: aq. H₂O₂ / methanol / 1 h / 20 °C

4.1: t-BuLi / pentane; tetrahydrofuran / 3.5 h / -100 - -70 °C

4.2: I₂ / pentane; tetrahydrofuran / 2 h / -70 - 0 °C

5.1: Cu / dimethylformamide / 4 h / 140 °C

With N-Bromosuccinimide; n-butyllithium; dihydrogen peroxide; tert.-butyl lithium; copper; In tetrahydrofuran; methanol; hexane; N,N-dimethyl-formamide; pentane; 5.1: Ullmann reaction;
DOI:10.1002/ejoc.200200634

Reference yield:

: 52287-51-1
6-bromo-1,4-benzodioxane

: 503538-67-8,445380-62-1,445467-62-9
[2,3,2',3'-tetrahydro-5,5'-bi(1,4-benzodioxin)-6,6'-diyl]bis-(diphenylphosphane oxide)

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 1.17 h / -78 °C

1.2: tetrahydrofuran; hexane / -70 - 0 °C

2.1: aq. H₂O₂ / methanol / 1 h / 20 °C

3.1: t-BuLi / pentane; tetrahydrofuran / 3.5 h / -100 - -70 °C

3.2: I₂ / pentane; tetrahydrofuran / 2 h / -70 - 0 °C

4.1: Cu / dimethylformamide / 4 h / 140 °C

With n-butyllithium; dihydrogen peroxide; tert.-butyl lithium; copper; In tetrahydrofuran; methanol; hexane; N,N-dimethyl-formamide; pentane; 4.1: Ullmann reaction;
DOI:10.1002/ejoc.200200634