thallium(III)⁽²⁴⁾Cl(6-C₆F₃H₂)2

Base Information

• Chemical Name: thallium(III)⁽²⁴⁾Cl(6-C₆F₃H₂)2
• CAS No.: 74625-70-0
• Molecular Formula: C₁₂H₄ClF₆Tl
• Molecular Weight: 501.99
• Mol file: 74625-70-0.mol

Synonyms:

Chemical Property of thallium(III)⁽²⁴⁾Cl(6-C₆F₃H₂)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of thallium(III)⁽²⁴⁾Cl(6-C₆F₃H₂)2

There total 2 articles about thallium(III)⁽²⁴⁾Cl(6-C₆F₃H₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

thallium (III) chloride (13453-32-2) + lithium-2,4,6-trifluorophenyl (53732-49-3) → thallium(III)(24)Cl(6-C6F3H2)2 (74625-70-0)

Guidance literature:

In diethyl ether; byproducts: LiCl; TlCl3 added to Li educt (1/2 molar ratio) soln. at -78°C under N2, stirred for 30 min, warmed slowly to room temp.; filtered, hydrolyzed with aq. HCl, org. layer removed, dried (MgSO4), evapd., recrystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1016/S0022-328X(00)96182-5

Reference yield: 70.0%

silver-2,4,6-trifluorophenyl (121772-59-6) + thallium (III) chloride (13453-32-2) → thallium(III)(24)Cl(6-C6F3H2)2 (74625-70-0)

Guidance literature:

In tetrahydrofuran; byproducts: AgCl; TlCl3 added to ether soln. of Ag-compd. (molar ratio 1:2), stirred 2h under N2, pptn. of AgCl; AgCl filtered off, soln. concd., n-hexane added, pptn.;

DOI:10.1016/0022-328X(89)87020-2

Reference yield: 70.0%

thallium(III)(24)Cl(6-C6F3H2)2 (74625-70-0) + Au(I)(C6F3H2)(tetrahydrothiophene) → gold(III)(C6F3H2)3(tetrahydrothiophene)

Guidance literature:

In toluene; byproducts: TlCl; stirring for 5 h at room temp., then refluxing for 3 h;; filtered; evapd.; pptd. from hexane; elem. anal.;;

DOI:10.1016/0022-328X(90)85199-9

upstream raw materials:

thallium (III) chloride

lithium-2,4,6-trifluorophenyl

silver-2,4,6-trifluorophenyl

Downstream raw materials:

Au(C₆F₅)(C₆F₃H₂)2(C₄H₈S)

Au(C₆F₃H₂)2ClP(C₆H₅)3

Bu₄N[Au(2,4,6-C₆F₃H₂)3Cl]

Refernces

• 1、 Uson, R.,Laguna, A.,Cuenca, T.. "CHLOROBIS(POLYFLUOROPHENYL)THALLIUM(III) COMPLEXES AND THEIR REACTIONS WITH GOLD(I) AND TIN(II) COMPOUNDS". . p. 271 - 276. Retrieved 2007/10/02.