Thallium(III) chloride

Base Information

• Chemical Name: Thallium(III) chloride
• CAS No.: 13453-32-2
• Molecular Formula: Cl3Tl
• Molecular Weight: 310.742
• European Community (EC) Number: 236-625-2
• Wikipedia: Thallium(III) chloride
• Mol file: 13453-32-2.mol

Synonyms:trichlorothallane;Thallium(III) chloride;Thallium(III) chloride hydrate;13453-32-2;Thallium chloride(TlCl3), tetrahydrate (9CI);TlCl3;Thallium( cento) chloride;EINECS 236-625-2

Chemical Property of Thallium(III) chloride

Chemical Property:

• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 155°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: g/cm³
• LogP: -9.05230
• Water Solubility.: very soluble H2O, alcohols, ether [KIR83]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 309.88099
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: Cl[Tl](Cl)Cl

Technology Process of Thallium(III) chloride

There total 36 articles about Thallium(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

thallium (III) oxide → thallium (III) chloride (13453-32-2)

Guidance literature:

With hydrogenchloride; In not given; rather concd. HCl, boiling;;

Reference yield: 98.5%

thionyl chloride (7719-09-7) + thallium chloride (55172-29-7,7791-12-0) + chlorine (7782-50-5) → thallium (III) chloride (13453-32-2)

Guidance literature:

In acetonitrile; TlCl suspd. in CH3CN; Cl2 added under vigorous stirring; stirred for 30 min; soln. filtered; solvent evapd. in vacuum; SOCl2 added; evapd. after 10 min;

DOI:10.1002/zaac.200600092

Reference yield:

monophenylthallium dichloride (19628-33-2) → thallium (III) chloride (13453-32-2) + phenylmercury(II) chloride (100-56-1)

Guidance literature:

With mercury dichloride; In water;

upstream raw materials:

nitrosylchloride

thallium chloride

chlorochromate(VI) ion

thallium nitrite

Downstream raw materials:

iodine

thallium chloride

thallium(I) thiocyanate

bismuth(III) chloride

Refernces

• 1、 Partington, J. R.,Whynes, A. L.. "". . . Retrieved 1948.
• 2、 Gurnani, Chitra,Jura, Marek,Levason, William,Ratnani, Raju,Reid, Gillian,Webster, Michael. "Synthesis, characterisation and structures of thio-, seleno- and telluro-ether complexes of indium(III) halides". . p. 1611 - 1619. Retrieved 2009/05/30.
• 3、 Woolf, Alfred A.. "Reactivity of Sulphuryl Chloride in Acetonitrile with the Elements". . p. 3325 - 3330. Retrieved 2007/10/02.