bis(triphenylphosphine)iminium tricarbonyl[1,2,2',η-(2-methylenepentane-2-one)yl]ferrate(-1)

Base Information

• Chemical Name: bis(triphenylphosphine)iminium tricarbonyl[1,2,2',η-(2-methylenepentane-2-one)yl]ferrate(-1)
• CAS No.: 69972-22-1
• Molecular Formula: C₉H₉FeO₄*C₃₆H₃₀NP₂
• Molecular Weight: 775.603
• Mol file: 69972-22-1.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)iminium tricarbonyl[1,2,2',η-(2-methylenepentane-2-one)yl]ferrate(-1)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)iminium tricarbonyl[1,2,2',η-(2-methylenepentane-2-one)yl]ferrate(-1)

There total 1 articles about bis(triphenylphosphine)iminium tricarbonyl[1,2,2',η-(2-methylenepentane-2-one)yl]ferrate(-1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

ethyl bromide (74-96-4) + disodium tetracarbonylferrate + 1,2-propanediene (463-49-0) + bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphine)iminium tricarbonyl[1,2,2',η-(2-methylenepentane-2-one)yl]ferrate(-1) (69972-22-1)

Guidance literature:

In tetrahydrofuran; (inert gas); propadiene dissolved at -5°C in complex soln., C2H5Br soln. added dropwise for 0.5 h, stirred for 1 h at room temp.; filtered, evapd., dissolved in CH2Cl2, (Ph3P)2NCl/CH2Cl2 added, stirredfor 1 h, filtered, pptd. (ether), filtered, crystd. (ether/CH2Cl2 at -20°C); elem. anal.;

DOI:10.1016/S0022-328X(00)86667-X

upstream raw materials:

ethyl bromide

1,2-propanediene

bis(triphenylphosphine)iminium chloride