(S)-(2-mercaptoethyl){2-(methoxymethyl)phenyl}methylarsine

Base Information

Chemical Name:(S)-(2-mercaptoethyl){2-(methoxymethyl)phenyl}methylarsine
CAS No.:108344-24-7
Molecular Formula:C₁₁H₁₇AsOS
Molecular Weight:272.243
Hs Code.:

Synonyms:

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Chemical Property of (S)-(2-mercaptoethyl){2-(methoxymethyl)phenyl}methylarsine

Chemical Property:

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Technology Process of (S)-(2-mercaptoethyl){2-(methoxymethyl)phenyl}methylarsine

There total 6 articles about (S)-(2-mercaptoethyl){2-(methoxymethyl)phenyl}methylarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: {SP-4,3-{(S),(R)}}-{dimethyl(1-(2-naphthyl)ethyl)aminato-C⁽²⁾,N}{(methyl(2-(methoxymethyl)phenyl)arsino)ethanethiolato-As,S}palladium(II)

: 108344-24-7,108344-25-8,108448-47-1
(R)-(2-mercaptoethyl){2-(methoxymethyl)phenyl}methylarsine

Guidance literature:: In dichloromethane; reaction of (S(As),R)-Pd compd. dissolved in CH2Cl2 with excess of NaCN in H2O over 12 h, the colorless organic layer was washed with H2O, dilute H2SO4 and H2O again, dried over MgSO4 and then distilled;; obtained as colorless oil; (1)HNMR;;
DOI:10.1021/ja00248a030

Reference yield:

: 52711-30-5
1-bromo-2-(methoxymethyl)benzene

: 108344-24-7,108344-25-8,108448-47-1
(+/-)-(2-mercaptoethyl)<2-(methoxymethyl)phenyl>methylarsine

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) magnesium / 1.) THF, 2.) 1 rt, 1 h, reflux 30 min

2: 93 percent / bromine / CH₂Cl₂ / 0 °C

3: 96.5 percent / 2 h / 160 °C

4: 92 percent / NaI / acetone

5: 1.) sodium / 1.) THF, 20 deg C, 5 h, 2.) 30 min

With bromine; sodium; magnesium; sodium iodide; In dichloromethane; acetone;
DOI:10.1021/ja00248a030

Reference yield:

: 57170-60-2
dimethyl<2-(methoxymethyl)phenyl>arsine

: 108344-24-7,108344-25-8,108448-47-1
(+/-)-(2-mercaptoethyl)<2-(methoxymethyl)phenyl>methylarsine

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / bromine / CH₂Cl₂ / 0 °C

2: 96.5 percent / 2 h / 160 °C

3: 92 percent / NaI / acetone

4: 1.) sodium / 1.) THF, 20 deg C, 5 h, 2.) 30 min

With bromine; sodium; sodium iodide; In dichloromethane; acetone;
DOI:10.1021/ja00248a030