57170-60-2Relevant academic research and scientific papers
Optically Active Arsenic Macrocycles. Stereospecific Syntheses of Enantiomers and Diastereomers of 14-Membered trans As2S2 Chelating Macrocycles Containing Resolved Asymmetric Tertiary Arsine Donors
Kerr, Philip G.,Leung, Pak-Hing,Wild, S. Bruce
, p. 4321 - 4328 (1987)
The first optically active macrocycles containing arsenic, (R,R)- and (S,S)-1, have been synthesized by template dimerizations of the enantiomers of deprotonated (+/-)-(2-mercaptoethyl)methylarsine, (+/-)-3, on palladium(II) with
