C₃₁H₅₂O₆Si

Base Information

• Chemical Name: C₃₁H₅₂O₆Si
• CAS No.: 1300655-94-0
• Molecular Formula: C₃₁H₅₂O₆Si
• Molecular Weight: 548.836
• Mol file: 1300655-94-0.mol

Synonyms:

Chemical Property of C₃₁H₅₂O₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₁H₅₂O₆Si

There total 12 articles about C₃₁H₅₂O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C13H18O2 (1300655-86-0) → C31H52O6Si (1300655-94-0)

Guidance literature:

Multi-step reaction with 9 steps

1.1: n-butyllithium / hexane; tert-butyl methyl ether / 0.17 h / -78 °C / Inert atmosphere

1.2: 0.67 h / 0 - 20 °C / Inert atmosphere

2.1: sodium hydride / hexane / 2 h / Inert atmosphere; Reflux

3.1: acetylacetonatodicarbonylrhodium(l) / benzene / 4.5 h / 60 °C / 51716.2 Torr / Autoclave

3.2: 1 h / 40 °C / Inert atmosphere

4.1: 2,6-dimethylpyridine / dichloromethane / 1 h / -78 °C / Inert atmosphere

5.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

5.2: -78 - 20 °C / Inert atmosphere

6.1: toluene / 18 h / Inert atmosphere; Reflux

7.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; citric acid / tetrahydrofuran; tert-butyl alcohol / 24 h / Inert atmosphere

8.1: sodium periodate; sodium hydrogencarbonate / tetrahydrofuran; water / 1 h / 0 °C / Inert atmosphere

9.1: tetra-(n-butyl)ammonium iodide / dichloromethane; water / 3 h / Inert atmosphere

With 2,6-dimethylpyridine; acetylacetonatodicarbonylrhodium(l); sodium periodate; osmium(VIII) oxide; n-butyllithium; water; tetra-(n-butyl)ammonium iodide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; 4-methylmorpholine N-oxide; citric acid; In tetrahydrofuran; hexane; dichloromethane; tert-butyl methyl ether; water; toluene; tert-butyl alcohol; benzene; 9.1: Felkin addition;

DOI:10.1021/ja201467z

Reference yield:

C21H32O4 (1300655-89-3) → C31H52O6Si (1300655-94-0)

Guidance literature:

Multi-step reaction with 6 steps

1.1: 2,6-dimethylpyridine / dichloromethane / 1 h / -78 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

3.1: toluene / 18 h / Inert atmosphere; Reflux

4.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; citric acid / tetrahydrofuran; tert-butyl alcohol / 24 h / Inert atmosphere

5.1: sodium periodate; sodium hydrogencarbonate / tetrahydrofuran; water / 1 h / 0 °C / Inert atmosphere

6.1: tetra-(n-butyl)ammonium iodide / dichloromethane; water / 3 h / Inert atmosphere

With 2,6-dimethylpyridine; sodium periodate; osmium(VIII) oxide; water; tetra-(n-butyl)ammonium iodide; diisobutylaluminium hydride; sodium hydrogencarbonate; 4-methylmorpholine N-oxide; citric acid; In tetrahydrofuran; hexane; dichloromethane; water; toluene; tert-butyl alcohol; 6.1: Felkin addition;

DOI:10.1021/ja201467z

Reference yield:

C27H46O4Si (1300655-90-6) → C31H52O6Si (1300655-94-0)

Guidance literature:

Multi-step reaction with 5 steps

1.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / -78 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: toluene / 18 h / Inert atmosphere; Reflux

3.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; citric acid / tetrahydrofuran; tert-butyl alcohol / 24 h / Inert atmosphere

4.1: sodium periodate; sodium hydrogencarbonate / tetrahydrofuran; water / 1 h / 0 °C / Inert atmosphere

5.1: tetra-(n-butyl)ammonium iodide / dichloromethane; water / 3 h / Inert atmosphere

With sodium periodate; osmium(VIII) oxide; water; tetra-(n-butyl)ammonium iodide; diisobutylaluminium hydride; sodium hydrogencarbonate; 4-methylmorpholine N-oxide; citric acid; In tetrahydrofuran; hexane; dichloromethane; water; toluene; tert-butyl alcohol; 5.1: Felkin addition;

DOI:10.1021/ja201467z

upstream raw materials:

C₁₃H₁₈O₂

C₂₁H₃₂O₄

C₂₇H₄₆O₄Si

C₂₇H₄₈O₄Si

Downstream raw materials:

C₃₄H₅₆O₈Si

C₄₁H₆₇NO₇S₂Si

C₃₆H₆₀O₈Si

C₃₆H₅₈N₄O₇SSi