Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2

Base Information

Chemical Name:Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2
CAS No.:147283-00-9
Molecular Formula:C₃₈H₄₈MoN₂
Molecular Weight:628.753
Hs Code.:

Mo(N-2,6-Pr(i)2C<sub>6</sub>H<sub>3</sub>)2(CH<sub>2</sub>Ph)2

Synonyms:

Suppliers and Price of Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2

There total 2 articles about Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 2785-29-7
benzyl potassium

: MoCl2(N(2,6-i-Pr2C6H3))2(1,2-dimethoxyethane)

: 147283-00-9
Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2

Guidance literature:: In tetrahydrofuran; diethyl ether; under N2: chilling of a soln. of Mo(NC6H3(CH(CH3)2)2)2Cl2(CH3OC2H4OCH3) in diethyl ether to -40°C; addn. of solid KCH2C6H5, then addn. of THF; stirring for 12 h;; removal of the volatiles under vac.; dissolving in ether; filtration through Celite; concn. in vac.; crystallization at -40°C; elem. anal.;;
DOI:10.1021/om00027a028

Reference yield: 60.0%

: 126949-60-8
Mo(N-2,6-Pr(i)2C₆H₃)2Cl₂ * dme

: 6921-34-2
benzylmagnesium chloride

: 147283-00-9
Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2

Guidance literature:: In diethyl ether; N2-atmosphere; dropwise addn. of 2 equiv. Grignard reagent to Mo-compd. (dry ice/Me2CO bath), stirring (room temp., 18 h); filtration, removal of volatiles (reduced pressure), crystn. (MeCN, -30°C); elem. anal.;
DOI:10.1016/S0022-328X(99)00452-0

Reference yield: 55.0%

: 110-71-4
1,2-dimethoxyethane

: 147283-00-9
Mo(N-2,6-Pr(i)2C₆H₃)2(CH₂Ph)2

: 1493-13-6
trifluorormethanesulfonic acid

: Mo(CHC₆H₅)(NC₆H₃(CH(CH₃)2)2)(OSO₂CF₃)2(CH₃OC₂H₄OCH₃)

Guidance literature:: In 1,2-dimethoxyethane; under N2: cooling a soln. of Mo-compound in DME to -40°C; addn. of triflic acid in DME; stirring for 16 h;; removal of DME under vac.; extraction with cold (-30°C) toluene; filtration through Celite; removing solvent in vac.; crystallization from ether; mixture of isomers with trans and cis triflate ligands obtained; elem. anal.;;
DOI:10.1021/om00027a028