Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(N'-acetyl-N-benzyl-hydrazino)-tetrahydro-pyran-4-yl ester

Base Information

• Chemical Name: Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(N'-acetyl-N-benzyl-hydrazino)-tetrahydro-pyran-4-yl ester
• CAS No.: 126946-47-2
• Molecular Formula: C₂₃H₃₀N₂O₁₀
• Molecular Weight: 494.499
• Mol file: 126946-47-2.mol

Synonyms:

Chemical Property of Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(N'-acetyl-N-benzyl-hydrazino)-tetrahydro-pyran-4-yl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(N'-acetyl-N-benzyl-hydrazino)-tetrahydro-pyran-4-yl ester

There total 4 articles about Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(N'-acetyl-N-benzyl-hydrazino)-tetrahydro-pyran-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

acetic anhydride (108-24-7) + C21H26N2O10 (126946-46-1) → Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(N'-acetyl-N-benzyl-hydrazino)-tetrahydro-pyran-4-yl ester (126946-47-2)

Guidance literature:

With acetic acid; zinc;

DOI:10.1039/c39890001640

Reference yield:

1,3,4,6-tetra-O-acetyl-D-glucosamine hydrochloride (5432-46-2,10034-19-2,10034-20-5,34948-62-4,110253-00-4,1191127-63-5) → Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(N'-acetyl-N-benzyl-hydrazino)-tetrahydro-pyran-4-yl ester (126946-47-2)

Guidance literature:

Multi-step reaction with 3 steps

1: K₂CO₃ / dimethylformamide

2: N₂O₄, NaOAc / CH₂Cl₂ / 0.08 h

3: 75 percent / Zn, AcOH

With sodium acetate; dinitrogen tetraoxide; potassium carbonate; acetic acid; zinc; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1039/c39890001640

Reference yield:

benzyl bromide (100-39-0) → Acetic acid (2S,3R,4R,5S,6R)-2,5-diacetoxy-6-acetoxymethyl-3-(N'-acetyl-N-benzyl-hydrazino)-tetrahydro-pyran-4-yl ester (126946-47-2)

Guidance literature:

Multi-step reaction with 3 steps

1: K₂CO₃ / dimethylformamide

2: N₂O₄, NaOAc / CH₂Cl₂ / 0.08 h

3: 75 percent / Zn, AcOH

With sodium acetate; dinitrogen tetraoxide; potassium carbonate; acetic acid; zinc; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1039/c39890001640

upstream raw materials:

acetic anhydride

C₂₁H₂₆N₂O₁₀

1,3,4,6-tetra-O-acetyl-D-glucosamine hydrochloride

benzyl bromide