Fe2(μ-SCH2-o-C6H4OMe)2(CO)6

Base Information

Chemical Name:Fe2(μ-SCH2-o-C6H4OMe)2(CO)6
CAS No.:1279025-68-1
Molecular Formula:C₂₂H₁₈Fe₂O₈S₂
Molecular Weight:586.206
Hs Code.:

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Chemical Property of Fe2(μ-SCH2-o-C6H4OMe)2(CO)6

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Technology Process of Fe2(μ-SCH2-o-C6H4OMe)2(CO)6

There total 1 articles about Fe2(μ-SCH2-o-C6H4OMe)2(CO)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: Fe2(μ-S)2(CO)6

: 52289-93-7
o-Methoxybenzyl bromide

: 1279025-68-1,1280227-75-9
Fe2(μ-SCH2-o-C6H4OMe)2(CO)6

Guidance literature:: With LiBHEt₃; In tetrahydrofuran; (Ar), soln. of Fe complex in dry THF precooled to -78°C treated with LiBHEt3 in dry THF, stirred for 30 min, treated with 2 equiv. of ligand, stirred at -78°C for 30 min, warmed to room temp. for 2 h; evapd., chromy.(flash - petroleum ether/EtOAc 20:1), elem. anal.;
DOI:10.1002/ejic.201001092

Reference yield: 58.2%

: 1279025-68-1,1280227-75-9
Fe2(μ-SCH2-o-C6H4OMe)2(CO)6

: 1279025-77-2,1280227-78-2
Fe2(μ-SCH2-o-C6H4OH)2(CO)6

Guidance literature:: With BBr₃; In dichloromethane; (Ar), precooled soln. of Fe complex in dry CH2Cl2 treated with soln. of BBr3 in dry CH2Cl2, stirred at -78°C for 2 h, warmed to room temp. for 6 h; cooled (ice-bath), evapd., chromy.(flash - ptroleum ether/EtOAc 10:1, 8:1, 5:1), elem. anal.;
DOI:10.1002/ejic.201001092