trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄COOMe)2]

Base Information

Chemical Name:trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄COOMe)2]
CAS No.:1278584-39-6
Molecular Formula:C₄₁H₃₄ClIrO₅P₂
Molecular Weight:896.338
Hs Code.:

trans-[Ir(CO)Cl(2-Ph<sub>2</sub>P-C<sub>6</sub>H<sub>4</sub>COOMe)2]

Synonyms:

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Chemical Property of trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄COOMe)2]

Chemical Property:

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Technology Process of trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄COOMe)2]

There total 1 articles about trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄COOMe)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 12246-51-4
[IrCl(cyclooctene)₂]₂

: 201230-82-2
carbon monoxide

: 79932-99-3
methyl 2-diphenylphosphinobenzoate

: 1278584-39-6
trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄COOMe)2]

Guidance literature:: In dichloromethane; acetonitrile; (Ir(COE)2Cl)2 (0.223 mmol) dissolved in CH3CN, stirred at room temp. for10 min under N2, N2 flow stopped, CO passed into soln. until clear gree nish yellow soln. obtained, soln. of 2-(Ph2P)-C6H4COOCH3 (0.897 mmol) inCH2Cl2 added, stirred for 30 min; evapn. under vac., residue washed with Et2O, recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1002/ejic.201001005

Reference yield:

: 1278584-39-6
trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄COOMe)2]

: trans-[Ir(O₂)(CO)Cl(2-Ph₂P-C₆H₄COOMe)2]

Guidance literature:: With air; In dichloromethane; air passed into soln. of trans-(Ir(CO)Cl(2-Ph2PC6H4COOMe)2) in CH2Cl2 atroom temp. under stirring for >6 h;
DOI:10.1002/ejic.201001005

Reference yield:

: 1278584-39-6
trans-[Ir(CO)Cl(2-Ph₂P-C₆H₄COOMe)2]

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 1278584-42-1
[Ir(CO)ClI₂(2-Ph₂P-C₆H₄COOMe)2]

Guidance literature:: In dichloromethane; under N2; I2 added to soln. of trans-(Ir(CO)Cl(2-Ph2P-C6H4COOMe)2) in CH2Cl2, mixt. stirred at room temp. for 2 h; evapn. under vac., residue washed with hexane; elem. anal.;
DOI:10.1002/ejic.201001005