[W2Cp2(μ-COMe)(μ-PPh2)2(CN-t-Bu)2]BF4

Base Information

Chemical Name:[W2Cp2(μ-COMe)(μ-PPh2)2(CN-t-Bu)2]BF4
CAS No.:1043628-03-0
Molecular Formula:BF₄*C₄₆H₅₁N₂OP₂W₂
Molecular Weight:1164.38
Hs Code.:

Synonyms:

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Chemical Property of [W2Cp2(μ-COMe)(μ-PPh2)2(CN-t-Bu)2]BF4

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Technology Process of [W2Cp2(μ-COMe)(μ-PPh2)2(CN-t-Bu)2]BF4

There total 1 articles about [W2Cp2(μ-COMe)(μ-PPh2)2(CN-t-Bu)2]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: [W2Cp2(μ-PPh2)2(μ-COMe)]BF4

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 1042977-55-8,1043628-03-0
[W2Cp2(μ-COMe)(μ-PPh2)2(CN-t-Bu)2]BF4

Guidance literature:: In dichloromethane; under N2; soln. of CN-t-Bu in CH2Cl2/petroleum ether added dropwise to soln. of W complex in CH2Cl2, mixt. stirred at room temp. for 10 min; evapn. under vac., residue washed with petroleum ether and dried under vac.; elem. anal.;
DOI:10.1021/om8002152

Reference yield: 88.0%

: 1042977-55-8,1043628-03-0
[W2Cp2(μ-COMe)(μ-PPh2)2(CN-t-Bu)2]BF4

: 201230-82-2
carbon monoxide

: 1042977-43-4
[W2Cp2(μ-COMe)(μ-PPh2)2(CO)(CN-t-Bu)]BF4

Guidance literature:: In 1,2-dichloro-ethane; bulb contg. soln. of W complex in 1,2-dichloroethane filled with CO at 77 K, valve closed, mixt. allowed to warm to room temp., stirred at 333 Kfor 2 h; evapn. under vac., residue dissolved in CH2Cl2, petroleum ether added, soln. concd., ppt. sepd. and washed with petroleum ether; elem. anal.;
DOI:10.1021/om8002152

Reference yield: 69.0%

: 1042977-55-8,1043628-03-0
[W2Cp2(μ-COMe)(μ-PPh2)2(CN-t-Bu)2]BF4

: 1042977-44-5
[W2Cp2(μ-COMe)(μ-PPh2)2(CN)(CN-t-Bu)]

Guidance literature:: With sodium amalgam; In tetrahydrofuran; under N2; soln. of W complex in THF and Na(Hg) stirred for 10 min, filtered, filtrate stirred for 2 h; evapn. under vac., residue chromd. (alumina (activity IV), CH2Cl2/petroleum ether 4/1); elem. anal.;
DOI:10.1021/om8002152