C₄₉H₅₇O₁₂P

Base Information

Chemical Name:C₄₉H₅₇O₁₂P
CAS No.:1388152-85-9
Molecular Formula:C₄₉H₅₇O₁₂P
Molecular Weight:868.958
Hs Code.:

C<sub>49</sub>H<sub>57</sub>O<sub>12</sub>P

Synonyms:

Suppliers and Price of C₄₉H₅₇O₁₂P

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₄₉H₅₇O₁₂P

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₄₉H₅₇O₁₂P

There total 22 articles about C₄₉H₅₇O₁₂P which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1388154-08-2
C₃₇H₄₈O₉

: 2524-64-3
chlorophosphoric acid diphenyl ester

: 1388152-85-9
C₄₉H₅₇O₁₂P

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane; In tetrahydrofuran; toluene; at -78 ℃; for 0.5h;
DOI:10.1021/ja305864z

Reference yield:

: 1264756-73-1
C₄₁H₆₀O₉Si

: 1388152-85-9
C₄₉H₅₇O₁₂P

Guidance literature:: Multi-step reaction with 20 steps

1.1: 20 % Pd(OH)2/C; hydrogen / tetrahydrofuran; methanol / 7.5 h / 20 °C

2.1: pyridinium p-toluenesulfonate / dichloromethane / 3 h / 20 °C

3.1: sodium hexamethyldisilazane / tetrahydrofuran; N,N-dimethyl-formamide / 0.5 h / 0 °C

3.2: 0.67 h / 0 °C

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 0 °C

5.1: pyridine / 1 h / 0 °C

6.1: silver nitrate; triethylamine / tetrahydrofuran; N,N-dimethyl-formamide / 0.08 h / 0 - 50 °C

6.2: 0.5 h / 0 - 20 °C

7.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.5 h / -78 °C / Inert atmosphere

8.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 0.5 h / 0 °C

9.1: tetrahydrofuran; diethyl ether / 0.67 h / 0 °C

10.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 2 h / 0 - 20 °C / Molecular sieve

11.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.5 h / 0 °C

11.2: 4.33 h / -78 - 20 °C

12.1: tetrahydrofuran / 1.75 h / 20 °C

13.1: dihydrogen peroxide; sodium hydrogencarbonate / tetrahydrofuran; water / 2 h / 0 - 20 °C

14.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 1 h / 0 °C

15.1: toluene / 20 h / 100 °C

16.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 20 h / 20 °C

17.1: diisobutylaluminium hydride / hexane; dichloromethane / 5 h / -78 - -40 °C / Inert atmosphere

18.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3.5 h / 0 - 20 °C

19.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane / 20 °C

20.1: N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; tetrapropylammonium perruthennate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; palladium 10% on activated carbon; 20 % Pd(OH)2/C; tetrabutyl ammonium fluoride; hydrogen; dihydrogen peroxide; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; potassium hexamethylsilazane; diisobutylaluminium hydride; sodium hydrogencarbonate; silver nitrate; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; water; dimethyl sulfoxide; ethyl acetate; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja305864z

Reference yield:

: 1388153-74-9
C₂₇H₄₈O₉Si

: 1388152-85-9
C₄₉H₅₇O₁₂P

Guidance literature:: Multi-step reaction with 19 steps

1.1: pyridinium p-toluenesulfonate / dichloromethane / 3 h / 20 °C

2.1: sodium hexamethyldisilazane / tetrahydrofuran; N,N-dimethyl-formamide / 0.5 h / 0 °C

2.2: 0.67 h / 0 °C

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 0 °C

4.1: pyridine / 1 h / 0 °C

5.1: silver nitrate; triethylamine / tetrahydrofuran; N,N-dimethyl-formamide / 0.08 h / 0 - 50 °C

5.2: 0.5 h / 0 - 20 °C

6.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.5 h / -78 °C / Inert atmosphere

7.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 0.5 h / 0 °C

8.1: tetrahydrofuran; diethyl ether / 0.67 h / 0 °C

9.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 2 h / 0 - 20 °C / Molecular sieve

10.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.5 h / 0 °C

10.2: 4.33 h / -78 - 20 °C

11.1: tetrahydrofuran / 1.75 h / 20 °C

12.1: dihydrogen peroxide; sodium hydrogencarbonate / tetrahydrofuran; water / 2 h / 0 - 20 °C

13.1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 1 h / 0 °C

14.1: toluene / 20 h / 100 °C

15.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 20 h / 20 °C

16.1: diisobutylaluminium hydride / hexane; dichloromethane / 5 h / -78 - -40 °C / Inert atmosphere

17.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3.5 h / 0 - 20 °C

18.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane / 20 °C

19.1: N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; tetrapropylammonium perruthennate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; dihydrogen peroxide; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; potassium hexamethylsilazane; diisobutylaluminium hydride; sodium hydrogencarbonate; silver nitrate; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; dimethyl sulfoxide; ethyl acetate; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja305864z