CH₃C₆₀(C₂)2(C₂₀H₇N₄)Ph₄Ni

Base Information

• Chemical Name: CH₃C₆₀(C₂)2(C₂₀H₇N₄)Ph₄Ni
• CAS No.: 904912-27-2
• Molecular Formula: C₁₀₉H₃₀N₄Ni
• Molecular Weight: 1454.15
• Mol file: 904912-27-2.mol

Synonyms:

Chemical Property of CH₃C₆₀(C₂)2(C₂₀H₇N₄)Ph₄Ni

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of CH₃C₆₀(C₂)2(C₂₀H₇N₄)Ph₄Ni

There total 1 articles about CH₃C₆₀(C₂)2(C₂₀H₇N₄)Ph₄Ni which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

nickel(II)-β-ethynyltetraphenylporphyrin (145565-50-0) + 1-ethynyl-9-methyl-1,9-dihydro(C60-Ih)[5,6]fullerene (182758-93-6) → CH3C60(C2)2(C20H7N4)Ph4Ni (904912-27-2)

Guidance literature:

With CuCl; tetramethylethylenediamine; O₂; In chlorobenzene; byproducts: ((Ph4(C20H7N4)Ni)C2)2; tetramethylethylenediamine (0.3 mmol), CuCl (2 mmol) added under dry O2 (room temp.) to sol. of C60C2HCH3 (19.7 μmol) and Zn porphyrin (59 μmol) in chlorobenzene (50 ml) stirred (room temp., 90 min); filtered through silica using CS2 as elunet; solvent removed (vac.); dissolved in CS2; placed on silica funnel; eluted with CS2; preparative TLC(silica gel, CS2);

DOI:10.1021/jp061844t

upstream raw materials:

nickel(II)-β-ethynyltetraphenylporphyrin

1-ethynyl-9-methyl-1,9-dihydro(C₆₀-Ih)[5,6]fullerene