Technology Process of nickel(II)-β-ethynyltetraphenylporphyrin
There total 3 articles about nickel(II)-β-ethynyltetraphenylporphyrin which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrabutylammonium fluoride;
In
tetrahydrofuran;
tetrabutylammonium fluoride (1.56 mmol) added to soln. of Ni porphyrin (0.13 mmol) in THF (vigorous stirring); kept (15 min); glacial acetic acid (1 ml) added; filtered through silica using CH2Cl2 as eluent;
DOI:10.1021/jp061844t
- Guidance literature:
-
Multi-step reaction with 3 steps
1: chloroform; methanol
2: triethylamine; bis(triphenylphosphine)palladium(II); CuI / triethylamine; N,N-dimethyl-formamide
3: tetrabutylammonium fluoride / tetrahydrofuran
With
triethylamine; bis(triphenylphosphine)palladium(II); CuI; tetrabutylammonium fluoride;
In
tetrahydrofuran; methanol; chloroform; triethylamine; N,N-dimethyl-formamide;
DOI:10.1021/jp061844t
- Guidance literature:
-
Multi-step reaction with 2 steps
1: triethylamine; bis(triphenylphosphine)palladium(II); CuI / triethylamine; N,N-dimethyl-formamide
2: tetrabutylammonium fluoride / tetrahydrofuran
With
triethylamine; bis(triphenylphosphine)palladium(II); CuI; tetrabutylammonium fluoride;
In
tetrahydrofuran; triethylamine; N,N-dimethyl-formamide;
DOI:10.1021/jp061844t
