trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]

Base Information

Chemical Name:trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]
CAS No.:681294-38-2
Molecular Formula:C₁₉H₂₀ClF₉N₂Pd
Molecular Weight:589.24
Hs Code.:

Synonyms:

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Chemical Property of trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]

Chemical Property:

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Technology Process of trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]

There total 4 articles about trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 175693-32-0
[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(cyclooctadiene)]

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 681294-38-2,681460-41-3
trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]

Guidance literature:: In acetone; all manipulations under dry N2; org. compd. added to soln. of Pd compd.,refluxed for 3 h; filtered, concd., hexane added, cooled to -20°C, decanted, washedwith n-hexane, dried in vac., elem. anal.;
DOI:10.1002/ejic.200300229

Reference yield:

: 681294-38-2,681460-41-3
cis-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]

: 681294-38-2,681460-41-3
trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]

Guidance literature:: In neat (no solvent, solid phase); by storage at room temp. for several wk; monitored by 19F NMR;
DOI:10.1002/ejic.200300229

Reference yield:

: 175693-32-0
[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(cyclooctadiene)]

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 681294-38-2,681460-41-3
cis-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]

: 681294-38-2,681460-41-3
trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(CNtBu)2]

Guidance literature:: In dichloromethane; all manipulations under dry N2; org. compd. added to soln. of Pd compd.at -50°C; monitored by 19F NMR, ratio of cis/trans compds. 72:28;
DOI:10.1002/ejic.200300229