2-[Bis(1-adamantyl)phosphino]biphenyl

Base Information

Chemical Name:2-[Bis(1-adamantyl)phosphino]biphenyl
CAS No.:224311-55-1
Molecular Formula:C₃₂H₃₉P
Molecular Weight:454.635
Hs Code.:
European Community (EC) Number:803-343-1
Nikkaji Number:J1.124.979E

Synonyms:224311-55-1;(2-Biphenyl)di-1-adamantylphosphine;2-[Bis(1-adamantyl)phosphino]biphenyl;Bis(1-adamantyl)-(2-phenylphenyl)phosphane;[1,1'-Biphenyl]-2-yldi(adamantan-1-yl)phosphine;[1,1'-Biphenyl]-2-yldi[(3S,5S,7S)-1-adamantanyl]phosphine;SCHEMBL4433788;MSKLBRMTWIUCEQ-UHFFFAOYSA-N;2-(di-1-adamantylphosphino)biphenyl;2-(di- 1-adamantylphosphino)biphenyl;(2-Biphenyl)di-1-adamantylphosphine, 97%;CS-0108697;E81299

Suppliers and Price of 2-[Bis(1-adamantyl)phosphino]biphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
(2-Biphenyl)di-1-adamantylphosphine 97%
1g
$ 292.00

Sigma-Aldrich
(2-Biphenyl)di-1-adamantylphosphine 97%
250mg
$ 82.40

Total 16 raw suppliers

Chemical Property of 2-[Bis(1-adamantyl)phosphino]biphenyl

Chemical Property:

Melting Point:220-225°C
XLogP3:8.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:454.278938242
Heavy Atom Count:33
Complexity:619

Purity/Quality:

97% ^*data from raw suppliers

(2-Biphenyl)di-1-adamantylphosphine 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:T
Statements: 23/24/25-36/37/38
Safety Statements: 36/37/39-45

MSDS Files:

Useful:

Canonical SMILES:C1C2CC3CC1CC(C2)(C3)P(C4=CC=CC=C4C5=CC=CC=C5)C67CC8CC(C6)CC(C8)C7
Uses Phosphine ligand for cross coupling.

Technology Process of 2-[Bis(1-adamantyl)phosphino]biphenyl

There total 2 articles about 2-[Bis(1-adamantyl)phosphino]biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2052-07-5
2-Bromobiphenyl

: 157282-19-4
di-1-adamantylchlorophosphane

: 224311-55-1
2-biphenyl

Guidance literature:: With magnesium; copper(I) chloride; In tetrahydrofuran; pentane;

Reference yield:

: 57680-77-0
adamantylmagnesium bromide

: 82214-69-5
2-biphenylmagnesium bromide

: 224311-55-1
2-biphenyl

Guidance literature:: With copper(l) chloride; phosphorus trichloride; Yield given; Multistep reaction; 1.) Et₂O, reflux, 22 h, 2.) THF, reflux, 3 h;
DOI:10.1021/ja990324r