1,4-dihydro-1,1,2,4,4,5-hexamethyl-3,6-diethyl-1,4-distannine

Base Information

• Chemical Name: 1,4-dihydro-1,1,2,4,4,5-hexamethyl-3,6-diethyl-1,4-distannine
• CAS No.: 106995-72-6
• Molecular Formula: C₁₄H₂₈Sn₂
• Molecular Weight: 433.796
• Mol file: 106995-72-6.mol

Synonyms:

Chemical Property of 1,4-dihydro-1,1,2,4,4,5-hexamethyl-3,6-diethyl-1,4-distannine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4-dihydro-1,1,2,4,4,5-hexamethyl-3,6-diethyl-1,4-distannine

There total 1 articles about 1,4-dihydro-1,1,2,4,4,5-hexamethyl-3,6-diethyl-1,4-distannine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(Z)-2-chloro(dimethyl)stannyl-3-diethylboryl-pent-2-ene (114644-07-4,101830-33-5) + lithium diethylamide (816-43-3) → 1,1,4,5,5-pentaethyl-2,2,3-trimethyl-2,5-dihydro-1,2,5-azoniastannaboratole (100581-13-3) + 1,4-dihydro-1,1,2,4,4,5-hexamethyl-3,6-diethyl-1,4-distannine (106995-72-6) + diethyl-diethylamino-borane (4023-39-6)

Guidance literature:

In hexane; byproducts: LiCl; Sn-complex in hexane was added (at -78°C) to a suspn. of LiNEt2 in hexane, mixt. was allowed to reach ambient temp. within 0.5 h, heated to reflux for 5 min; filtered, volatiles were removed, distilled (product contained < 2% NEt2SnMe2C2Me(Et)B(Et)2 before distn.);

DOI:10.1039/c39860001170

upstream raw materials:

(Z)-2-chloro(dimethyl)stannyl-3-diethylboryl-pent-2-ene

lithium diethylamide