zirconocene tert-butyl pentafluorophenoxide

Base Information

Chemical Name:zirconocene tert-butyl pentafluorophenoxide
CAS No.:1187043-19-1
Molecular Formula:C₂₀H₁₉F₅OZr
Molecular Weight:461.586
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of zirconocene tert-butyl pentafluorophenoxide

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Technology Process of zirconocene tert-butyl pentafluorophenoxide

There total 1 articles about zirconocene tert-butyl pentafluorophenoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 90491-53-5
zirconocene bis(pentafluorophenoxide)

: 594-19-4
tert.-butyl lithium

: 1187043-19-1
zirconocene tert-butyl pentafluorophenoxide

Guidance literature:: In diethyl ether; pentane; byproducts: C6F5OLi; under inert atmosphere; Zr complex dissolved in Et2O; cooled to -78°C; pentane soln. of t-BuLi added dropwise; stirred at -78°C for 2 h; gradually warmed to room temp.; stirred for 1 h; evapd. to dryness; hexane added; stirred; volatiles stripped off; extd. with hexane; filtered; dried under vac.; repeated twice; elem. anal.;
DOI:10.1021/om8008734

Reference yield:

: 1187043-19-1
zirconocene tert-butyl pentafluorophenoxide

: 1187043-25-9
zirconocene isobutyl pentafluorophenoxide

Guidance literature:: In benzene-d6; under inert atmosphere; soln. of Zr complex in benzene-d6 stored at 70°C for 3 h; monitored by (1)H NMR spectra; Kinetics;
DOI:10.1021/om8008734