Gold, [bis(2,4,6-trimethylphenyl)phosphine]chloro-

Base Information

• Chemical Name: Gold, [bis(2,4,6-trimethylphenyl)phosphine]chloro-
• CAS No.: 127690-37-3
• Molecular Formula: C18H23AuClP
• Molecular Weight: 502.774
• Mol file: 127690-37-3.mol

Synonyms:

Chemical Property of Gold, [bis(2,4,6-trimethylphenyl)phosphine]chloro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Gold, [bis(2,4,6-trimethylphenyl)phosphine]chloro-

There total 1 articles about Gold, [bis(2,4,6-trimethylphenyl)phosphine]chloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

carbonylgold(I) chloride (50960-82-2) + dimesityl phosphine (1732-66-7) → di(mesityl)phosphine-chloro-gold(I) (127690-37-3)

Guidance literature:

In diethyl ether; byproducts: CO; in carbon monoxide atmosphere; reaction temp.: 20°C; 10-50% excess of ligand is successful; reaction mixt. was evapd.; product was filtered; washed and dried; elem. anal.; IR; NMR;

Reference yield: 69.0%

di(mesityl)phosphine-chloro-gold(I) (127690-37-3) → [Au[P[(CH3)3C6H2]2]]4 (549514-47-8)

Guidance literature:

With aq. NH₄OH; In tetrahydrofuran; aq. NH4OH added to a soln. of Au-comp. in THF, stirred for 30 min; solv. removed, washed with H2O, elem. anal.;

DOI:10.1002/anie.200390270

upstream raw materials:

carbonylgold(I) chloride

dimesityl phosphine

Downstream raw materials:

[Au[P[(CH₃)3C₆H₂]2]]4