Chlorocarbonyl gold(I)

Base Information

• Chemical Name: Chlorocarbonyl gold(I)
• CAS No.: 50960-82-2
• Molecular Formula: CAuClO
• Molecular Weight: 260.43
• Hs Code.: 2915900090
• European Community (EC) Number: 686-956-5
• Mol file: 50960-82-2.mol

Synonyms:Chlorocarbonyl gold(I);50960-82-2;Chlorocarbonyl gold (I);chloromethanone;gold(1+);SCHEMBL1013971;A913412

Chemical Property of Chlorocarbonyl gold(I)

Chemical Property:

• Melting Point: 247-253°C (dec.)
• PSA: 0.00000
• LogP: 0.47900
• Storage Temp.: ?20°C
• Sensitive.: air sensitive, moisture sensitiv
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 259.930337
• Heavy Atom Count: 4
• Complexity: 15.5

Purity/Quality:

97% ^*data from raw suppliers

Chlorocarbonylgold(I), min. 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 20/21/22-36/37/38
• Safety Statements: 22-36/37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-](=O)Cl.[Au+]
• Uses: Gold Catalysts — 21st Century ′Gold Rush′

Technology Process of Chlorocarbonyl gold(I)

There total 3 articles about Chlorocarbonyl gold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

gold(III) chloride (13453-07-1) → phosgene (75-44-5) + carbonylgold(I) chloride (50960-82-2)

Guidance literature:

With carbon monoxide; chlorine;

DOI:10.1021/ja01370a052

Reference yield:

carbon monoxide (201230-82-2) + chlorine (7782-50-5) + gold(III) chloride (13453-07-1) → phosgene (75-44-5) + carbonylgold(I) chloride (50960-82-2)

Guidance literature:

byproducts: Au; streaming CO, 100°C;

DOI:10.1021/ja01370a052

Reference yield:

Au4Cl8 → phosgene (75-44-5) + carbonylgold(I) chloride (50960-82-2) + Au2Cl4(CO)

Guidance literature:

With CO; In thionyl chloride; molar ratio: 2 mol of CO per mol of Au4Cl8; products not isolated, detected by IR;

DOI:10.1039/DT9820002257

upstream raw materials:

gold(III) chloride

carbon monoxide

chlorine

Downstream raw materials:

chloro(2-methyl-5-phenyl-1,2,4,3σ(2)-triazaphosphole)gold(I)

gold

phosgene

gold(I) chloride