bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II)

Base Information

Chemical Name:bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II)
CAS No.:868240-97-5
Molecular Formula:C₅₂H₆₀FeO₂P₂
Molecular Weight:834.842
Hs Code.:

Synonyms:

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Chemical Property of bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II)

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Technology Process of bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II)

There total 4 articles about bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: dimethyltetrakis(trimethylphosphane)iron(II)

: 185509-32-4
(2-diphenylphosphanyl-4,6-di(tert-butyl))phenol

: 868240-97-5
bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II)

: bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P](trimethylphosphane)iron(II)

Guidance literature:: In diethyl ether; byproducts: CH4, P(CH3)3; under Ar; Fe complex and phosphine dissolved in Et2O at -70°C, mixt. warmed to 20°C, soln. stirred for 12 h; evapd. under vac., residue extd. with pentane, crystn. at -5°C, Fe(OC6H2(C(CH3)3)2(P(C6H5)2))2 isolated from concd. mother liquor by cooling at -78°C;, elem. anal.;
DOI:10.1002/zaac.200500021

Reference yield: 65.0%

: hydrido[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]tris(trimethylphosphane)iron(II)

: 868240-97-5
bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II)

Guidance literature:: With CH₃I; In diethyl ether; under Ar; mixt. of Fe complex and MeI in Et2O stirred for 72 h; white solid sepd., liquid evapd. under vac., residue extd. with pentane,crystn.; elem. anal.,;
DOI:10.1002/zaac.200500021

Reference yield: 37.0%

: 944728-30-7,55853-16-2
bis(trimethylphosphino)iron(II) chloride

: 185509-32-4
(2-diphenylphosphanyl-4,6-di(tert-butyl))phenol

: 868240-97-5
bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II)

: bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P](trimethylphosphane)iron(II)

Guidance literature:: With diisopropylamine; In diethyl ether; byproducts: P(CH3)3, (NH2(CH(CH3)2)2)Cl; under Ar; Fe complex, phosphine, and diisopropylamine dissolved in THF at -70°C, mixt. warmed to 20°C, soln. stirred for 19 h; evapd. under vac., residue extd. with pentane, crystn. at -5°C, Fe(OC6H2(C(CH3)3)2(P(C6H5)2))2 isolated from concd. mother liquor by cooling at -78°C;, elem. anal.;
DOI:10.1002/zaac.200500021