bis(trimethylphosphino)iron(II) chloride

Base Information

Chemical Name:bis(trimethylphosphino)iron(II) chloride
CAS No.:944728-30-7
Molecular Formula:C₆H₁₈Cl₂FeP₂
Molecular Weight:278.909
Hs Code.:

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Chemical Property of bis(trimethylphosphino)iron(II) chloride

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Technology Process of bis(trimethylphosphino)iron(II) chloride

There total 1 articles about bis(trimethylphosphino)iron(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: C₂₇H₄₂FeP₄Se

: 944728-30-7,55853-16-2
bis(trimethylphosphino)iron(II) chloride

: C₃₉H₃₇FeP₃Se₂

Guidance literature:: In tetrahydrofuran; diethyl ether; at -78 ℃; for 0.5h; Schlenk technique;
DOI:10.1016/j.jorganchem.2017.10.037

Reference yield: 37.0%

: 944728-30-7,55853-16-2
bis(trimethylphosphino)iron(II) chloride

: lithium cyclopentadienide

: 102-54-5,55404-68-7
ferrocene

: chloro(η-cyclopentadienyl)bis(trimethylphosphine)iron

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; dropwise addn. of CpLi in THF to (PMe3)2FeCl2 in THF under Ar at 20°C;; evapn. of THF; dissolving in pentane; filtration; dissolving of the solid in CH2Cl2; filtration from LiCl; pptn. from filtrate by addn. of pentane, repeating operation; elem. anal.; Cp2Fe from the pentane filtrate and the THF distillate by sublimation;;

Reference yield: 37.0%

: 944728-30-7,55853-16-2
bis(trimethylphosphino)iron(II) chloride

: 185509-32-4
(2-diphenylphosphanyl-4,6-di(tert-butyl))phenol

: 868240-97-5
bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P]iron(II)

: bis[2-(diphenylphosphanyl)-4,6-di-tert-butylphenolato-O,P](trimethylphosphane)iron(II)

Guidance literature:: With diisopropylamine; In diethyl ether; byproducts: P(CH3)3, (NH2(CH(CH3)2)2)Cl; under Ar; Fe complex, phosphine, and diisopropylamine dissolved in THF at -70°C, mixt. warmed to 20°C, soln. stirred for 19 h; evapd. under vac., residue extd. with pentane, crystn. at -5°C, Fe(OC6H2(C(CH3)3)2(P(C6H5)2))2 isolated from concd. mother liquor by cooling at -78°C;, elem. anal.;
DOI:10.1002/zaac.200500021